A free-standing and flexible phosphorus/nitrogen dual-doped three-dimensional reticular porous carbon frameworks encapsulated cobalt phosphide with superior performance for nitrite detection in drinking water and sausage samples
“…Along with the increasing concerns of the environmental pollution and the urgent need of renewable energy sources, [1–9] Supercapacitors (SCs) emerge as a compelling green energy solution with superior specific capacitance, prominent rate performance, high power density, and an extended lifetime [10–17] . Relying on charge storage mechanisms, SCs have been generally classified into electrical double‐layer‐type capacitors (EDLCs) and pseudocapactive‐type capacitors (PCs) [15–19] . Recently, increasing research efforts have focused on discovering pseudocapactive materials in view of these remarkable properties [20–24] …”
Oxygen defects and hollow structures positively impact pseudocapacitive properties of diffusion/surface‐controlled processes, a component of critical importance when building high‐performance supercapacitors. Hence, we fabricated hollow nickel/cobalt molybdate rods with O‐defects (D−H−NiMoO4@CoMoO4) through a soft‐template and partial reduction method, enhancing D−H−NiMoO4@CoMoO4’s electrochemical performance, yielding a specific capacitance of 1329 F g−1, and demonstrating excellent durability with 95.8 % capacity retention after 3000 cycles. D−H−NiMoO4@CoMoO4 was used as the positive electrode to construct an asymmetric supercapacitor, displaying an energy density of up to 34.13 Wh kg−1 and demonstrating good predisposition towards practical applications. This work presents an effective approach to fabricate and use hollow nickel/cobalt molybdate rods with O‐defects as pseudocapacitor material for high‐performance capacitive energy storage devices.
“…Along with the increasing concerns of the environmental pollution and the urgent need of renewable energy sources, [1–9] Supercapacitors (SCs) emerge as a compelling green energy solution with superior specific capacitance, prominent rate performance, high power density, and an extended lifetime [10–17] . Relying on charge storage mechanisms, SCs have been generally classified into electrical double‐layer‐type capacitors (EDLCs) and pseudocapactive‐type capacitors (PCs) [15–19] . Recently, increasing research efforts have focused on discovering pseudocapactive materials in view of these remarkable properties [20–24] …”
Oxygen defects and hollow structures positively impact pseudocapacitive properties of diffusion/surface‐controlled processes, a component of critical importance when building high‐performance supercapacitors. Hence, we fabricated hollow nickel/cobalt molybdate rods with O‐defects (D−H−NiMoO4@CoMoO4) through a soft‐template and partial reduction method, enhancing D−H−NiMoO4@CoMoO4’s electrochemical performance, yielding a specific capacitance of 1329 F g−1, and demonstrating excellent durability with 95.8 % capacity retention after 3000 cycles. D−H−NiMoO4@CoMoO4 was used as the positive electrode to construct an asymmetric supercapacitor, displaying an energy density of up to 34.13 Wh kg−1 and demonstrating good predisposition towards practical applications. This work presents an effective approach to fabricate and use hollow nickel/cobalt molybdate rods with O‐defects as pseudocapacitor material for high‐performance capacitive energy storage devices.
“…Compared to these methods, the electrochemical method, as a new detection method, has its own attracted advantages, such as: simple-operation, short-time and low-cost and so on. [43,44] Because of the tunable redox properties, POM-based CPs materials could be used as an inexpensive amperometric sensors for detecting Cr [4-atrz = (4amino-triazole)] with variable POMs by a one-step hydrothermal synthesis method(Scheme 1). The main reasons for choosing this reaction system as follows: (i) Copper is a 3d transition metal, which has coordination diversity and flexibility.…”
The development of POM‐based coordination polymers (CPs) provides a promising chance to approach excellent bifunctional electrode materials. Herein, three new polyoxometalates (POMs)‐based three‐dimensional (3D) inorganic‐organic hybrid compounds, [HPMVI9MV3O40]CuI5[4‐atrz]6⋅XH2O [M=Mo(1) or W(2), X=1(1)], [H2SiMoVI9MoV3O40]CuI5[4‐atrz]6⋅H2O (3) have been synthesized via hydrothermal reaction and explored as pseudocapacitive and sensors electrode materials. These compounds possess a novel three‐dimensional sandwich structure formed from POMs and ring CuI‐4‐atrz complexes by using Cu1 as nodes. As capacitor electrode materials, compounds 1 and 3 with Mo‐containing POMs show much higher specific capacitance than 2, which is because that POMs with Mo as metal atoms have much higher oxidation capacity than those with W. When these compounds are used as sensors to detect NO2− and Cr2O72−, compound 3 shows the highest sensitivity, lowest detection limit and most excellent anti‐interference ability. These results indicate that combining POMs and CuI‐4‐atrz complexes to form POM‐based coordination polymers with unique microstructures greatly improve the electrochemical performance and stability of traditional POMs as electrode materials, which are attributed to excellent redox properties of POMs, and unique three‐dimensional structure formed due to introduction of Cu‐4‐atrz complex. This work provides a promising direction for exploring novel bifunctional electrode materials.
“…Researchers have prepared and amended different techniques to fabricate excellent catalysts, such as 2D NiCoFe, 1 cobalt phosphates (Co 3 (PO 4 ) 2 ), 2 (Co 5 (PO 4 ) 2 (OH) 4 ), 3 Fe 2 O 3 , 4 CuCo 2 S 4 /g-C 3 N 4 , 5 Co 2 -P@FePO 4 , 6 Au/ZnO, 7 Au/Cu, 8 Co 2 P/Co 2 N, 9 and DNA@Mn 3 (PO 4 ) 2 . 10 Among them, porous nanostructured materials, with high porosity, have exhibited impressive properties in several applications, for example catalysis, 6,[11][12][13][14] separation, 6,15 energy storage materials, [16][17][18] sensors, [19][20][21] and drug delivery. [22][23][24] Numerous synthesis methods, such as hydrothermal, 1 polymerization, 6 co-precipitation, 25,26 electrodeposition, 27,28 and direct calcination methods, 2 were utilized to prepare porous nanostructured materials.…”
Among the accessible techniques, the production of hydrogen by electrocatalytic water oxidation is the most established process, which comprises oxygen evolution reaction (OER) and hydrogen evolution reaction (HER).
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