Since
highly stretchable hydrogels have demonstrated their promising
applications in flexible tactile sensors and wearable devices, the
current challenge has been imposed on stretchable and multifunctional
electronics. Here, we report a multifunctional sensor composed of
a liquid metal (LM) nanodroplet-adhered self-assembled polymeric network,
anionic carboxymethylcellulose (CMC), and cationic polyacrylamide
(PAAm). The synergistic effect, zeta potential reduction, by CMC and
macromolecules enveloped by LM contributes to the stabilization of
the ternary system during preparation and, thus, the homogenization
of the products. By engineering and optimizing the ternary hybrid
hydrogels, excellent extensibility (tensile strain near 300%), readily
reversible hysteresis loops, and accessible deformability (low modulus
of 104 Pa) are afforded. The fabricated sensor exhibits
a high tensile strain gauge factor of around 0.7 and a high compressive
stress sensitivity of up to 0.12 kPa–1, a fast response
time below 125 ms, and a high stability and precision in usage. In
a series of practical scenarios, the assembled sensor displays distinguished
abilities to monitor bodily motions, record electrocardiograms, authenticate
handwriting, discern temperature, and infer materials, making them
highly promising for multifunctional intelligent soft sensing.