A five coordination Cu(ii) cluster-based MOF and its application in the synthesis of pharmaceuticals via sp³ C–H/N–H oxidative coupling

Abstract

Five coordination sites of Cu(ii) cluster were found in VNU-18 that showed highly efficient catalytic property for the oxidative C–H activation via N–H bonds.

Kinetics, Isotherm, Thermodynamics, and Recyclability of Exfoliated Graphene-Decorated MnFe2O4 Nanocomposite Towards Congo Red Dye

“…Figure 1, the profile of EG material witnessed a sharp peak at 26.6°, which was highly commensurate with previous publications, proving that EG has been successfully synthesized [27]. At a glance, the figure for MnFe 2 O 4 Materials. To gain more understanding about the morphological properties of EG@ MnFe 2 O 4 material, the SEM technique can be used.…”

“…Research interest in nanomaterials (metalorganic frameworks, nanoparticles, porous nanomaterials, etc.) has become an integral part in the development of future technologies [1][2][3][4]. Among these, multiferroic nanomaterials (e.g., MFe 2 O 4 , M stands for transition metals) have afforded an abundance of widely practical applications, hence, giving rise in research interests, especially in environmental remediation [5,6].…”

Engineering Metal–Organic Framework Catalysts for C−C and C−X Coupling Reactions: Advances in Reticular Approaches from 2014–2018

“…Prototype A 3 coupling (a) and Pechmannc ondensation (b) reactions. [70].Copyright 2017, The Royal Society of Chemistry). Friedlander reaction catalyzedbyh omochiral NbO-type Cu MOF.…”

Combined Minimum-Run Resolution IV and Central Composite Design for Optimized Removal of the Tetracycline Drug Over Metal–Organic Framework-Templated Porous Carbon

“…More specifically, Table S2 lists the twenty-trial actual and predicted values for the TCC removal. The highest percentage of TCC removal was 93.0% (entry 3), while the lowest was only 53.0% (entry 14) and the average six trials were 79.8% (entries [15][16][17][18][19][20]. The empirical relationships between the response (Y) and the significant factors (A, B, and C) were achieved from using a central composite design via the Design-Expert®Software [47]:…”

“…Recently, such mesoporous carbons (MPC) can be facilely synthesized via the pyrolysis of metal-organic frameworks (MOFs) as self-sacrificial templates [15][16][17][18]. The MOFs are highly crystalline and porous materials, constructed by iron clusters and organic ligands, giving them excellent tailorability and versatile functionalities [19][20][21][22]. Due to tailoring the electron-rich functionalized adsorbents via these MOFs precursors, applications of MOFs-derived porous carbons (PCs) have been widened, especially in the removal of antibiotics.…”