A Field Comparison of 'Total Suspended Particles' and PM<sub>10</sub>'Air Samplers in Collecting Polycyclic Aromatic Hydrocarbons

Menichini, Edoardo; Monfredini, Fabio

doi:10.1080/03067319508027245

Cited by 9 publications

(1 citation statement)

References 11 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Particulate-phase PAHs, OPAHs and NPAHs were sampled as PM 10 , while RPAHs were collected as TSP. The difference of PAC concentrations in TSP compared to PM 10 is expected to be non-significant as reported by Menichini and Monfredini (1995) and Ringuet et al (2012b) for PAHs and PAH derivatives due to low concentrations of PACs in coarse-mode particles. All the data are filtered for contamination with the stack of our research vessel (details given in Sect.…”

Section: Occurrence Of Pahs and Pah Derivativesmentioning

confidence: 84%

Polycyclic aromatic hydrocarbons (PAHs) and their alkylated, nitrated and oxygenated derivatives in the atmosphere over the Mediterranean and Middle East seas

et al. 2022

View full text Add to dashboard Cite

Abstract. Polycyclic aromatic hydrocarbons (PAHs) and their alkylated (RPAHs), nitrated (NPAHs) and oxygenated (OPAHs) derivatives are air pollutants. Many of these substances are long-lived, can undergo long-range atmospheric transport and adversely affect human health upon exposure. However, the occurrence and fate of these air pollutants have hardly been studied in the marine atmosphere. In this study, we report the atmospheric concentrations over the Mediterranean Sea, the Red Sea, the Arabian Sea, the Gulf of Oman and the Arabian Gulf, determined during the AQABA (Air Quality and Climate Change in the Arabian Basin) project, a comprehensive ship-borne campaign in summer 2017. The average concentrations of ∑26PAHs, ∑19RPAHs, ∑11OPAHs and ∑17NPAHs, in the gas and particulate phases, were 2.99 ± 3.35 ng m−3, 0.83 ± 0.87 ng m−3, 0.24 ± 0.25 ng m−3 and 4.34 ± 7.37 pg m−3, respectively. The Arabian Sea region was the cleanest for all substance classes, with concentrations among the lowest ever reported. Over the Mediterranean Sea, we found the highest average burden of ∑26PAHs and ∑11OPAHs, while the ∑17NPAHs were most abundant over the Arabian Gulf (known also as the Persian Gulf). 1,4-Naphthoquinone (1,4-O2NAP) followed by 9-fluorenone and 9,10-anthraquinone were the most abundant studied OPAHs in most samples. The NPAH composition pattern varied significantly across the regions, with 2-nitronaphthalene (2-NNAP) being the most abundant NPAH. According to source apportionment investigations, the main sources of PAH derivatives in the region were ship exhaust emissions, residual oil combustion and continental pollution. All OPAHs and NPAHs except 2-nitrofluoranthene (2-NFLT), which were frequently detected during the campaign, showed elevated concentrations in fresh shipping emissions. In contrast, 2-NFLT and 2-nitropyrene (2-NPYR) were highly abundant in aged shipping emissions due to secondary formation. Apart from 2-NFLT and 2-NPYR, benz(a)anthracene-7,12-dione and 2-NNAP also had significant photochemical sources. Another finding was that the highest concentrations of PAHs, OPAHs and NPAHs were found in the sub-micrometre fraction of particulate matter (PM1).

show abstract

Section: Occurrence Of Pahs and Pah Derivativesmentioning

confidence: 84%

Polycyclic aromatic hydrocarbons (PAHs) and their alkylated, nitrated and oxygenated derivatives in the atmosphere over the Mediterranean and Middle East seas

et al. 2022

View full text Add to dashboard Cite

show abstract

Levels and distributions of organic source tracers in air and roadside dust particles of Kuala Lumpur, Malaysia

et al. 2007

View full text Add to dashboard Cite

Relationships between indoor and outdoor air pollution by carcinogenic PAHs and PCBs

Menichini

Iacovella

Monfredini

et al. 2007

Atmospheric Environment

View full text Add to dashboard Cite

A Field Comparison of 'Total Suspended Particles' and PM₁₀'Air Samplers in Collecting Polycyclic Aromatic Hydrocarbons

Cited by 9 publications

References 11 publications

Polycyclic aromatic hydrocarbons (PAHs) and their alkylated, nitrated and oxygenated derivatives in the atmosphere over the Mediterranean and Middle East seas

Polycyclic aromatic hydrocarbons (PAHs) and their alkylated, nitrated and oxygenated derivatives in the atmosphere over the Mediterranean and Middle East seas

Levels and distributions of organic source tracers in air and roadside dust particles of Kuala Lumpur, Malaysia

Relationships between indoor and outdoor air pollution by carcinogenic PAHs and PCBs

Contact Info

Product

Resources

About

A Field Comparison of 'Total Suspended Particles' and PM10'Air Samplers in Collecting Polycyclic Aromatic Hydrocarbons

Cited by 9 publications

References 11 publications

Polycyclic aromatic hydrocarbons (PAHs) and their alkylated, nitrated and oxygenated derivatives in the atmosphere over the Mediterranean and Middle East seas

Polycyclic aromatic hydrocarbons (PAHs) and their alkylated, nitrated and oxygenated derivatives in the atmosphere over the Mediterranean and Middle East seas

Levels and distributions of organic source tracers in air and roadside dust particles of Kuala Lumpur, Malaysia

Relationships between indoor and outdoor air pollution by carcinogenic PAHs and PCBs

Contact Info

Product

Resources

About

A Field Comparison of 'Total Suspended Particles' and PM₁₀'Air Samplers in Collecting Polycyclic Aromatic Hydrocarbons