A facile synthetic route and dual function of network luminescent porous polyester and copolyester containing porphyrin moiety for metal ions sensor and dyes adsorption

Aly, Kamal I.; Sayed, Marwa M.; Mohamed, Mohamed Gamal; Kuo, Shiao‐Wei; Younis, Osama

doi:10.1016/j.micromeso.2020.110063

Cited by 64 publications

(22 citation statements)

References 57 publications

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“…The preparation of porous organic polymers (POPs) has become a hot topic in the academic and industry fields due to their interesting features, such as high physicochemical stability, porous character, low density, facile preparation, low regeneration energy, and good thermal and chemical stabilities [ 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 ]. Porous organic polymers have been applied in different applications such as light harvesting, chemical sensors, catalysis, iodine uptake, H 2 production from water, water treatment, optoelectronic devices, carbon dioxide reduction, nanofiltration, enantioseparation, energy storage, gas separation, and adsorption [ 14 , 15 , 16 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 , 28 , 29 ].…”

Section: Introductionmentioning

confidence: 99%

Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO2 Uptake and Iodine Adsorption

et al. 2021

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In this study, two different types of hybrid porous organic polymers (POPs), polyhedral oligomeric silsesquioxane tetraphenylpyrazine (POSS-TPP) and tetraphenylethene (POSS-TPE), were successfully synthesized through the Friedel−Crafts polymerization of tetraphenylpyrazine (TPP) and tetraphenylethene (TPE), respectively, with octavinylsilsesquioxane (OVS) as node building blocks, in the presence of anhydrous FeCl3 as a catalyst and 1,2-dichloroethane at 60 °C. Based on N2 adsorption and thermogravimetric analyses, the resulting hybrid porous materials displayed high surface areas (270 m2/g for POSS-TPP and 741 m2/g for POSS-TPE) and outstanding thermal stabilities. Furthermore, as-prepared POSS-TPP exhibited a high carbon dioxide capacity (1.63 mmol/g at 298 K and 2.88 mmol/g at 273 K) with an excellent high adsorption capacity for iodine, reaching up to 363 mg/g, compared with the POSS-TPE (309 mg/g).

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Section: Introductionmentioning

confidence: 99%

Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO2 Uptake and Iodine Adsorption

et al. 2021

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“…Based on the supercapacitors mechanism for energy storage, supercapacitors can be divided into electrical double layer capacitor (EDLC), hybrid capacitor, and finally pseudocapacitor [ 16 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 , 26 , 27 ]. Hyper-crosslinked polymers (HCPs) [ 28 , 29 , 30 , 31 , 32 , 33 ], covalent organic frameworks (COF) [ 34 , 35 , 36 , 37 , 38 , 39 , 40 ], conjugated microporous polymers (CMPs) [ 41 , 42 , 43 , 44 , 45 ], and polymers of intrinsic microporosity (PIMs) are considered as types of microporous organic polymers (MOPs) [ 46 , 47 , 48 , 49 ]. As mentioned above, HCPs are considered as a kind of porous material that can be easily synthesized through the Friedel–Crafts alkylation reaction of rigid aromatic monomers with an external crosslinker such as formaldehyde dimethyl acetal, 1,3,5-trichlorotriazine, and 1,4-bis(chloromethyl)benzene [ 50 , 51 , 52 ].…”

Section: Introductionmentioning

confidence: 99%

Meso/Microporous Carbons from Conjugated Hyper-Crosslinked Polymers Based on Tetraphenylethene for High-Performance CO2 Capture and Supercapacitor

Mohamed

Ahmed

et al. 2021

Molecules

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In this study, we successfully synthesized two types of meso/microporous carbon materials through the carbonization and potassium hydroxide (KOH) activation for two different kinds of hyper-crosslinked polymers of TPE-CPOP1 and TPE-CPOP2, which were synthesized by using Friedel–Crafts reaction of tetraphenylethene (TPE) monomer with or without cyanuric chloride in the presence of AlCl3 as a catalyst. The resultant porous carbon materials exhibited the high specific area (up to 1100 m2 g−1), total pore volume, good thermal stability, and amorphous character based on thermogravimetric (TGA), N2 adsoprtion/desorption, and powder X-ray diffraction (PXRD) analyses. The as-prepared TPE-CPOP1 after thermal treatment at 800 °C (TPE-CPOP1-800) displayed excellent CO2 uptake performance (1.74 mmol g−1 at 298 K and 3.19 mmol g−1 at 273 K). Furthermore, this material possesses a high specific capacitance of 453 F g−1 at 5 mV s−1 comparable to others porous carbon materials with excellent columbic efficiencies for 10,000 cycle at 20 A g−1.

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“…In favorable cases, the immobilization of fluorescent molecules in the solid matrix may reduce intra-molecular motions and rearrangements, which leads to enhanced photostability and fluorescence capability. Porphyrins can be used as highly sensitive indicators [ 100 ]. In 1990, R. Czolk et al [ 101 ] have begun developing fiber optic sensors for the detection of heavy metal ions using porphyrins.…”

Section: Construction Of Porphyrin-based Materials For Metal Ions mentioning

confidence: 99%

Recent Advances in Porphyrin-Based Materials for Metal Ions Detection

Cheng

et al. 2020

IJMS

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Porphyrins have planar and conjugated structures, good optical properties, and other special functional properties. Owing to these excellent properties, in recent years, porphyrins and their analogues have emerged as a multifunctional platform for chemical sensors. The rich chemistry of these molecules offers many possibilities for metal ions detection. This review mainly discusses two types of molecular porphyrin and porphyrin composite sensors for metal ions detection, because porphyrins can be functionalized to improve their functional properties, which can introduce more chemical and functional sites. According to the different application materials, the section of porphyrin composite sensors is divided into five sub-categories: (1) porphyrin film, (2) porphyrin metal complex, (3) metal–organic frameworks, (4) graphene materials, and (5) other materials, respectively.

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A facile synthetic route and dual function of network luminescent porous polyester and copolyester containing porphyrin moiety for metal ions sensor and dyes adsorption

Cited by 64 publications

References 57 publications

Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO2 Uptake and Iodine Adsorption

Multifunctional Polyhedral Oligomeric Silsesquioxane (POSS) Based Hybrid Porous Materials for CO2 Uptake and Iodine Adsorption

Meso/Microporous Carbons from Conjugated Hyper-Crosslinked Polymers Based on Tetraphenylethene for High-Performance CO2 Capture and Supercapacitor

Recent Advances in Porphyrin-Based Materials for Metal Ions Detection

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