2018
DOI: 10.3390/pr6050059
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A Facile Synthesis of Hexagonal Spinel λ-MnO2 Ion-Sieves for Highly Selective Li+ Adsorption

Abstract: Abstract:Ion-sieves are a class of green adsorbent for extraction Li + from salt lakes. Here, we propose a facile synthesis of hexagonal spinel LiMn 2 O 4 (LMO) precursor under mild condition which was first prepared via a modified one-pot reduction hydrothermal method using KMnO 4 and ethanol. Subsequently, the stable spinel structured λ-MnO 2 (HMO) were prepared by acidification of LMO. The as-prepared HMO shows a unique hexagonal shape and can be used for rapid adsorption-desorption process for Li + adsorpt… Show more

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Cited by 37 publications
(12 citation statements)
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References 28 publications
(45 reference statements)
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“…The recent research contains various methods for reducing the impact of azo dyes on public health and environmental quality. Common classes of techniques are physical-based (adsorption, ion exchange, membrane filtration [2][3][4][5][6]), chemical-based (ozonation, electrochemical degradation, advanced oxidation processes), and biological-based (biodegradation, bioaccumulation, biosorption using fungi, algae, yeast, and bacteria) [7][8][9][10]. Due to the many drawbacks presented in conventional wastewater treatment technologies (high operation costs, energy consumption, reduced efficiency due to the chemical stability of dyes and/or the complexity of their degradation), the recent trend is to combine the techniques for sustainability, as oxidation/catalysis or adsorption/catalysis, etc.…”
Section: Introductionmentioning
confidence: 99%
“…The recent research contains various methods for reducing the impact of azo dyes on public health and environmental quality. Common classes of techniques are physical-based (adsorption, ion exchange, membrane filtration [2][3][4][5][6]), chemical-based (ozonation, electrochemical degradation, advanced oxidation processes), and biological-based (biodegradation, bioaccumulation, biosorption using fungi, algae, yeast, and bacteria) [7][8][9][10]. Due to the many drawbacks presented in conventional wastewater treatment technologies (high operation costs, energy consumption, reduced efficiency due to the chemical stability of dyes and/or the complexity of their degradation), the recent trend is to combine the techniques for sustainability, as oxidation/catalysis or adsorption/catalysis, etc.…”
Section: Introductionmentioning
confidence: 99%
“…An important question, which needs to be clearly answered, is: why apply adsorption for the decontamination of effluents? Recently, adsorption has been widely applied on wastewater decontamination [5][6][7][8][9], mainly because of its removal efficiency from dilute solutions. Usual materials like activated carbon [10], chitosan [11], zeolite, and clay [12] are still in high demand due to their great adsorption capacity, but these are relatively costly.…”
Section: Introductionmentioning
confidence: 99%
“…selectivity and desorbed by some solvents, thereby separating Li ? from other coexisting ions [53]. The key to this method is identifying excellent adsorption materials with high Li ?…”
Section: Adsorption Extraction Materialsmentioning
confidence: 99%