A Facile Strategy for Synthesizing Organic Tannic Metal Salts as Advanced Energy Storage Anodes

Liu, Fang; Liao, Song-Yi; Lin, Hai; Yin, Yawen; Liu, Yidong; Meng, Hong; Min, Yong

doi:10.1002/celc.202100569

Cited by 9 publications

(7 citation statements)

References 63 publications

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“…The capacity and Coulombic efficiency from the 26th cycle onward tended to remain nearly constant, indicating the good stability and capacity retention of the Fe-CP anode after standing for 5 days. On the basis of the above results, it can be stated that the Fe-CP contains competitive high-performance anode materials in comparison to other typical anode materials in LIBs ( Table 1 ) [ 46 , 47 , 48 , 49 , 50 , 51 , 52 , 53 , 54 , 55 , 56 , 57 , 58 , 59 , 60 , 61 , 62 , 63 , 64 , 65 , 66 , 67 , 68 , 69 , 70 ]. These findings highlight the exceptional potential of 1D structure materials for lithium storage, offering enhanced performance and reliability for LIBs.…”

Section: Resultsmentioning

confidence: 80%

One-Dimensional Croconate-Based Fe-CP as a High-Performance Anode Material for Lithium–Ion Batteries

Zhang,

Gui

2023

Polymers

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Coordination polymers (CPs) have attracted greater scientific attention as promising electrode materials for lithium–ion batteries (LIBs) due to their diverse and versatile structural chemistry. This study introduces a croconate-based one-dimensional CP, namely [Fe(C5O5)(H2O)3]n) (referred to as Fe-CP), as an efficient anode material with high-performance characteristics for rechargeable LIBs. The ligand with abundant redox sites coordinating to the transition metal ion endowed the anode material with a remarkable stability in the electrolyte, in addition to high capacity, high-rate capability, and high cycling performance during charging/discharging process. The Fe-CP has a unique chain-based supramolecular structure, setting it apart from other porous three-dimensional molecular materials. The presence of unrestricted channels between the chains facilitates the diffusion of lithium ions in this unique structure. When tested at 100 mA g−1 over a range of voltages between 0.01 and 2.4 V, the Fe-CP anode demonstrated a noteworthy specific capacity of 521 mA h g−1 over 140 cycles. Moreover, the Fe-CP anode material exhibited excellent rate performance and demonstrated favorable cyclability. Following exposure to high charging and discharging rates of 2 A g−1, the anode ultimately regained its initial capability when the current rate was back at 100 mA g−1.

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Section: Resultsmentioning

confidence: 80%

One-Dimensional Croconate-Based Fe-CP as a High-Performance Anode Material for Lithium–Ion Batteries

Zhang,

Gui

2023

Polymers

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“…The intensity of the peaks becomes stronger as the reaction proceeds, which also indicates good reversibility of the association/disassociation of the Na atom with the lignin anode. [ 26 ] Figure 2a demonstrates the second scan CV curves of the lignin anode at two different operating temperatures. A wave with a small, broad cathodic peak at ≈1.8 V is present on both CV curves.…”

Section: Resultsmentioning

confidence: 99%

Natural Lignin: A Sustainable and Cost‐Effective Electrode Material for High‐Temperature Na‐Ion Battery

She

Zheng

et al. 2023

Energy & Environ Materials

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Rechargeable sodium‐ion batteries usually suffer from accelerated electrode destruction at high temperatures and high synthesis costs of electrode materials. Therefore, it is highly desirable to explore novel organic electrodes considering their cost‐effectiveness and large adaptability to volume changes. Herein, natural biomass, pristine lignin, is employed as the sodium‐ion battery anodes, and their sodium storage performance is investigated at room temperature and 60 °C. The lignin anodes exhibit excellent high‐temperature sodium‐ion battery performance. This mainly results from the generation of abundant reactive sites (C=O) due to the high temperature‐induced homogeneous cleavage of the Cβ–O bond in the lignin macromolecule. This work can inspire researchers to explore other natural organic materials for large‐scale applications and high‐value utilization in advanced energy storage devices.

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“…The authors have cited additional references in Supporting Information. [29][30][31][32][33][34][35][36][37][38][39][40]…”

Section: Supporting Informationmentioning

confidence: 99%

A Naphthalenetetracarboxdiimide‐Containing Covalent Organic Polymer: Preparation, Single Crystal Structure and Battery Application

Dong,

Naren,

Zhang

et al. 2024

Angew Chem Int Ed

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Inspired by dative boron‐nitrogen (B←N) bonds proven to be the promising dynamic linkage for the construction of crystalline covalent organic polymers/frameworks (COPs/COFs), we employed 1,4‐bis(benzodioxaborole) benzene (BACT) and N,N'‐Di(4‐pyridyl)‐1,4,5,8‐naphthalenetetracarboxdiimide (DPNTCDI) as the corresponding building blocks to construct a functional COP (named as CityU‐25), which had been employed as an anode in rechargeable lithium ion batteries. CityU‐25 displayed an excellent reversible lithium storage capability of 455 mAh/g after 170 cycles at 0.1 A/g, and an impressive one of 673 mAh/g after 720 cycles at 0.5 A/g. These findings suggest that CityU‐25 is a standout candidate for advanced battery technologies, highlighting the potential application of this type of materials

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A Facile Strategy for Synthesizing Organic Tannic Metal Salts as Advanced Energy Storage Anodes

Cited by 9 publications

References 63 publications

One-Dimensional Croconate-Based Fe-CP as a High-Performance Anode Material for Lithium–Ion Batteries

One-Dimensional Croconate-Based Fe-CP as a High-Performance Anode Material for Lithium–Ion Batteries

Natural Lignin: A Sustainable and Cost‐Effective Electrode Material for High‐Temperature Na‐Ion Battery

A Naphthalenetetracarboxdiimide‐Containing Covalent Organic Polymer: Preparation, Single Crystal Structure and Battery Application

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