One-Dimensional Croconate-Based Fe-CP as a High-Performance Anode Material for Lithium–Ion Batteries

Abstract

Coordination polymers (CPs) have attracted greater scientific attention as promising electrode materials for lithium–ion batteries (LIBs) due to their diverse and versatile structural chemistry. This study introduces a croconate-based one-dimensional CP, namely [Fe(C5O5)(H2O)3]n) (referred to as Fe-CP), as an efficient anode material with high-performance characteristics for rechargeable LIBs. The ligand with abundant redox sites coordinating to the transition metal ion endowed the anode material with a remarkable stability in the electrolyte, in addition to high capacity, high-rate capability, and high cycling performance during charging/discharging process. The Fe-CP has a unique chain-based supramolecular structure, setting it apart from other porous three-dimensional molecular materials. The presence of unrestricted channels between the chains facilitates the diffusion of lithium ions in this unique structure. When tested at 100 mA g−1 over a range of voltages between 0.01 and 2.4 V, the Fe-CP anode demonstrated a noteworthy specific capacity of 521 mA h g−1 over 140 cycles. Moreover, the Fe-CP anode material exhibited excellent rate performance and demonstrated favorable cyclability. Following exposure to high charging and discharging rates of 2 A g−1, the anode ultimately regained its initial capability when the current rate was back at 100 mA g−1.