A difluoro-substituted oxyallyl intermediate in [4 + 3]cycloadditions with cyclopentadiene and furan

Föhlisch, Baldur; Radl, Andreas

doi:10.1016/s0022-1139(98)00122-5

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Cited by 3 publications

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“…A few examples of the (4+3)-cycloaddition of a fluorinated oxyallyl have been published. 17 Results were generally only Scheme 1 Synthesis of a GABA analogue using the (4+3)-cycloaddition reaction.…”

Section: ð1þmentioning

confidence: 99%

The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

Harmata

2010

Chem. Commun.

219

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The (4+3)-cycloaddition of allylic cations to dienes is a powerful method for the direct synthesis of seven-membered rings. Recent developments in this area have included new methods for the generation of allylic cations, diastereoselective and catalytic, enantioselective reactions, an increased understanding of the diverse mechanistic possibilities of the reaction and applications to the total synthesis of natural products and their analogues.

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Section: ð1þmentioning

confidence: 99%

The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

Harmata

2010

Chem. Commun.

219

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[m+n(+…)] Cycloaddition

2010

Comprehensive Organic Name Reactions and Reagents

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The cycloaddition reaction is an important reaction in organic synthesis, in which two or more molecules combine and form new ring structures, along with the formation of multiple bonds and multiple stereogenic centers in a single step. Besides this, cycloadditions are also considered the right choice when high regioselectivities, chemoselectivities and stereoselectivities are concerned. The present study represents various types of cycloadditions reactions and their mechanism currently used in organic syntheses.

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ChemInform Abstract: A Difluoro‐Substituted Oxyallyl Intermediate in [4 + 3] Cycloadditions with Cyclopentadiene and Furan.

Foehlisch

Radl

1998

ChemInform

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A difluoro-substituted oxyallyl intermediate in [4 + 3]cycloadditions with cyclopentadiene and furan

Cited by 3 publications

References 23 publications

The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

The (4+3)-cycloaddition reaction: heteroatom-substituted allylic cations as dienophiles

[m+n(+…)] Cycloaddition

ChemInform Abstract: A Difluoro‐Substituted Oxyallyl Intermediate in [4 + 3] Cycloadditions with Cyclopentadiene and Furan.

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