A critical review of solid phase microextraction for analysis of water samples

Piri‐Moghadam, Hamed; Ahmadi, Fardin; Pawliszyn, Janusz

doi:10.1016/j.trac.2016.05.029

Cited by 170 publications

(49 citation statements)

References 154 publications

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“…An equilibrium process takes place either in headspace or direct immersion extraction mode, during which the analyte partitions between the SPME coating and the sample matrix. SPME was first used to absorb analytes from solution, but the technique has since been applied to extract contaminants from both air and water samples . It is also useful in concentrating compounds such as β ‐blockers, illicit drugs, and immunosuppressive drugs from blood, urine and tissue, and in some such cases direct sampling was performed in vivo .…”

Section: Introductionmentioning

confidence: 99%

“…SPME was first used to absorb analytes from solution, 30,31 but the technique has since been applied to extract contaminants from both air and water samples. 32,33 It is also useful in concentrating compounds such as β-blockers, 34 illicit drugs, 35 and immunosuppressive drugs from blood, 36 urine and tissue, and in some such cases direct sampling was performed in vivo. 37 The amount of analyte concentrated on the SPME fiber is directly proportional to its concentration in the sample.…”

Section: Introductionmentioning

confidence: 99%

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Rapid quantification of acetaminophen in plasma using solid‐phase microextraction coupled with thermal desorption electrospray ionization mass spectrometry

Shiea

Bhat

et al. 2019

Rapid Comm Mass Spectrometry

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Rationale Solid‐phase microextraction coupled with thermal desorption electrospray ionization tandem mass spectrometry (SPME‐TD‐ESI‐MS/MS) is proposed as a novel method for the rapid quantification of acetaminophen in plasma samples from a pharmacokinetics (PK) study. Methods Traces of acetaminophen were concentrated on commercial fused‐silica fibers coated with a polar polyacrylate (PA) polymer using direct immersion SPME. No agitation, heating, addition of salt, or adjustment of the pH of the sample solution was applied during the extraction. Any acetaminophen absorbed on the SPME fibers was subsequently desorbed and detected by TD‐ESI‐MS/MS. Results Parameters of the absorption, sensitivity, reproducibility, and linearity for the SPME‐TD‐ESI‐MS/MS method were evaluated. The time required to complete a TD‐ESI‐MS/MS analysis was less than 30 seconds. Matrix‐matching calibration was performed to calculate the concentration of acetaminophen in the sample. A linear calibration curve with a concentration range of 100–10,000 ng/mL was constructed to calculate the quantity of acetaminophen. The SPME‐TD‐ESI‐MS quantification results for acetaminophen in plasma were in good agreement with those obtained by the conventional LC/MS/MS method. Conclusions With the proposed method, a 10‐min SPME time was enough to achieve the lower limit of quantitation (i.e. 100 ng/mL) and for a complete PK profiling of acetaminophen. A shorter extraction time could be achieved by applying agitation, heating, adding salt, or adjusting the pH of the sample solution to enhance analyte absorption efficiency. The time required to detect acetaminophen on the SPME fiber was less than 30 s, allowing the rapid quantification of acetaminophen in plasma with good accuracy.

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Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Rapid quantification of acetaminophen in plasma using solid‐phase microextraction coupled with thermal desorption electrospray ionization mass spectrometry

Shiea

Bhat

et al. 2019

Rapid Comm Mass Spectrometry

View full text Add to dashboard Cite

show abstract

“…However, SPME is not a completely solvent-free technique when combined with HPLC because small volumes of the organic solvent are necessary for desorption of the analytes from the fiber prior to HPLC separation. Numerous reviews have presented the applications of SPME in the analysis of various samples, e.g., [91][92][93][94][95][96][97][98][99][100][101][102][103][104]. Table 2 illustrates some representative examples of SPME applications.…”

Section: Solid Phase Microextraction (Spme)mentioning

confidence: 99%

Green Approaches to Sample Preparation Based on Extraction Techniques

Aly

Górecki

2020

Molecules

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Preparing a sample for analysis is a crucial step of many analytical procedures. The goal of sample preparation is to provide a representative, homogenous sample that is free of interferences and compatible with the intended analytical method. Green approaches to sample preparation require that the consumption of hazardous organic solvents and energy be minimized or even eliminated in the analytical process. While no sample preparation is clearly the most environmentally friendly approach, complete elimination of this step is not always practical. In such cases, the extraction techniques which use low amounts of solvents or no solvents are considered ideal alternatives. This paper presents an overview of green extraction procedures and sample preparation methodologies, briefly introduces their theoretical principles, and describes the recent developments in food, pharmaceutical, environmental and bioanalytical chemistry applications.

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“…Sample preparation is a critical step to ensure the appropriate selectivity and sensitivity in analytical methods [1–5]. The number of required sample preparation steps depends on each analytical method and the complexity of the matrix of the sample.…”

Section: Introductionmentioning

confidence: 99%

3D Printing in analytical sample preparation

Ceballos

Balavandy

et al. 2020

J of Separation Science

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In the last 5 years, additive manufacturing (three-dimensional printing) has emerged as a highly valuable technology to advance the field of analytical sample preparation. Three-dimensional printing enabled the cost-effective and rapid fabrication of devices for sample preparation, especially in flow-based mode, opening new possibilities for the development of automated analytical methods. Recent advances involve membrane-based three-dimensional printed separation devices fabricated by print-pause-print and multi-material three-dimensional printing, or improved three-dimensional printed holders for solid-phase extraction containing sorbent bead packings, extraction disks, fibers, and magnetic particles. Other recent developments rely on the direct three-dimensional printing of extraction sorbents, the functionalization of commercial three-dimensional printable resins, or the coating of three-dimensional printed devices with functional micro/nanomaterials. In addition, improved devices for liquid-liquid extraction such as extraction chambers, or phase separators are opening new possibilities for analytical method development combined with high-performance liquid chromatography. The present review outlines the current state-of-the-art of three-dimensional printing in analytical sample preparation. K E Y W O R D S3D printing, liquid-liquid extraction, membrane separation, sample preparation, solid-phase extraction 1854

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A critical review of solid phase microextraction for analysis of water samples

Cited by 170 publications

References 154 publications

Rapid quantification of acetaminophen in plasma using solid‐phase microextraction coupled with thermal desorption electrospray ionization mass spectrometry

Rapid quantification of acetaminophen in plasma using solid‐phase microextraction coupled with thermal desorption electrospray ionization mass spectrometry

Green Approaches to Sample Preparation Based on Extraction Techniques

3D Printing in analytical sample preparation

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