A Critical Interpretation and Quantitative Extension of the Sama-Szargut Second Law Rules in an Extended Exergy Perspective

Abstract

Twenty-five years ago, Gaggioli, Sama and Qian published a series of 10 "second law guidelines" for design and process engineers, nicknamed at that time "the Gaggioli-Sama rules". These guidelines, some of them previously published by Sama between 1980 and 1983, are a compilation of "second law errors" to avoid in the design of energy conversion systems. The list was rearranged several times, until a revised version containing 21 rules was published by Sama and Szargut in 1995. Ever since, these guidelines came to be known as "the Sama-Szargut rules". The rules are a series of well-formulated and insightful suggestions that reflect a thermodynamicist's idea that the "best design" is the one that minimizes the overall irreversibility in a process or plant, under the prescribed technological constraints. Characteristically, the concept of "optimal system" is completely absent, the emphasis being on the extensive inclusion of second law reasoning into design decisions. A critical analysis of the rules would suggest that all of them be routinely implemented both in new designs and most important in retrofit projects. A survey of some of the current most common energy conversion installations shows that, quite on the contrary, most of the rules are disregarded in practical applications. This paper argues that the reason for this incongruency is the neglection in the engineering design decision of the real cost of installation, operation and decommissioning of a plant, and proposes a rephrasing of the rules in an extended exergy perspective: if the production cost, including the externalities, is measured in units of equivalent primary exergy, the Sama-Szargut rules can be directly interpreted in this sense, and abidance by the rules results in the reduction of the resource cost for any given objective. OPEN ACCESSEnergies 2014, 7 5358

Exergy analysis of reverse electrodialysis

“…Differently from energy, exergy is destroyed in real systems operation due to irreversible phenomena like heat exchange, uncontrolled mixing, friction or chemical reactions [17]. The assessment of exergy destruction due to irreversibility occurring within each component of a cycle provides fundamental information on the main limiting factors of the entire cycle, identifying possible design and operative improvements, in order to achieve profitable energy conversion and/or savings [18].…”