A cis-Oxo[diphenylhydrazido(2–)]molybdenum Complex: (Et3NH)2[MoO(NNPh2)(SC6H4CO2)2]

Li-Kao, J.; González, Óscar; Mariezcurrena, R. A.; Baggio, Ricardo; Garland, Marı́a Teresa; Carrillo, David

doi:10.1107/s0108270195006007

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Crystal Structures Of the Platinum And Nickel Complexes 1b A...1

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“…If the difference in radii for platinum and nickel is taken as 0.08 Å (based on the difference in the M᎐P bond lengths) then the Pt᎐S and Pt᎐O bonds are apparently longer than expected, since they are 0.15 and 0.23 Å longer than the corresponding Ni᎐S and Ni᎐O ones. In the 7 there are two different thiosalicylate ligands, one coplanar with the co-ordination plane as in the nickel complex 3b, and one slanted as in the platinum example 1b. The Mo᎐S/O distances to the slanted ligand are significantly longer than those to the coplanar ligand, so noncoplanarity appears generally to lead to a less tightly held ligand.…”

Section: Crystal Structures Of the Platinum And Nickel Complexes 1b A...mentioning

confidence: 99%