“…It seems that hypochlorite and luminol exhibit direct chemiluminescence (CL) under alkaline conditions without any catalyst. 32,33 This argument was confirmed by a blue luminescence seen on the surface of the BDD electrode directly after the addition of 10 mM NaClO without any potential applied (ESI; S2 †). Accordingly, it is concluded that the ECL signal was generated by the remaining luminol that did not react with hypochlorite through the CL reaction.…”
Section: Resultsmentioning
confidence: 72%
“…Having the same characteristic with H 2 O 2 as reactive oxygen species (ROS), 32,33 hypochlorite was expected to act as a coreactant in the ECL system; indeed it quenches the ECL signals. It seems that hypochlorite and luminol exhibit direct chemiluminescence (CL) under alkaline conditions without any catalyst.…”
Electrogenerated chemiluminescence (ECL) of luminol using boron-doped diamond electrode has been developed for hypochlorite determination. The presence of H2O2 induces the ECL signals of luminol. On the contrary, the presence...
“…It seems that hypochlorite and luminol exhibit direct chemiluminescence (CL) under alkaline conditions without any catalyst. 32,33 This argument was confirmed by a blue luminescence seen on the surface of the BDD electrode directly after the addition of 10 mM NaClO without any potential applied (ESI; S2 †). Accordingly, it is concluded that the ECL signal was generated by the remaining luminol that did not react with hypochlorite through the CL reaction.…”
Section: Resultsmentioning
confidence: 72%
“…Having the same characteristic with H 2 O 2 as reactive oxygen species (ROS), 32,33 hypochlorite was expected to act as a coreactant in the ECL system; indeed it quenches the ECL signals. It seems that hypochlorite and luminol exhibit direct chemiluminescence (CL) under alkaline conditions without any catalyst.…”
Electrogenerated chemiluminescence (ECL) of luminol using boron-doped diamond electrode has been developed for hypochlorite determination. The presence of H2O2 induces the ECL signals of luminol. On the contrary, the presence...
“…Nowadays, a number of uorescent probes have been successfully developed for detecting and imaging ClO À . [16][17][18][19] Compared with these traditional methods, the uorescent probe shows improved selectivity and sensitivity for ClO À detection in vitro and in vivo. 20 However, the most reported probes suffered from the complex synthesis, poor selectivity, low sensitivity and long response time.…”
A colorimetric NIR fluorescent probe for detecting ClO− has been synthesized. And it had outstanding advantages: one-step synthesis, high sensitivity , selectivity and successful application in actual water samples, living cells and zebrafish.
“…[16][17][18][19][20] For example, Kim and co-workers proposed a fluorescent probe for monitoring HClO in real water samples and living zebrafish by introducing an imine group into the benzothiazole skeleton. 21 Hou et al presented a new isophoronebased fluorescent probe for tracking HClO in living cells by employing dimethylthiocarbamate as the recognition group. 22 Zhou et al developed a red-emitting fluorescent probe that has the capability of imaging HClO in living cells upon oxidation of an amino group to a nitroso compound.…”
A simple yet highly effective camphor-derived fluorescent probe named 3-(anthracen-9-ylmethylene)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one oxime (ATHO) was developed based on the oxime recognition receptor and anthracene fluorophore. The probe ATHO displayed a remarkably enhanced...
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