A Basket‐Like [Sr⊂P₆Mo^V₄Mo^VI₁₄O₇₃]^10– Polyoxoanion Modified with {Cu(phen)(H₂O)_x} (x = 1–3) Fragments: Synthesis, Structure, Magnetic, and Electrochemical Properties

A new two-dimensional polyoxoniobate built by Lindqvist-type polyoxoanion and copper coordinated cations K2[Cu(H2O)6]{[Nb6O19][Cu(NH3)]2}·8H2O

“…The XPS spectrum exhibits two peaks at 934.0 and 954.5 eV, which can be attributed to Cu 2+ (2p 3/2 ) and Cu 2+ (2p 1/2 ), respectively. These values are in good agreement with the values reported in the literature [41].…”

Organic–Inorganic Hybrid Materials Based on Basket-like {Ca⊂P6Mo18O73} Cages

“…It is proved that the space size of the basket-like cluster tended to capture larger alkali metals or alkaline earth cations. 15,17 In fact, the incorporation of the large cations can also stabilize the basket-like cage.…”

A new [As3Mo3O15]3− fragment decorated with Cu(I)-imi (imi=imidazole) complexes: Synthesis, structure and electrochemical properties

“…Molybdenum arsenate fragments have a large number of terminal and bridge oxygen atoms that have the potential to combine with metal ions, so not only could molybdenum arsenate fragments coordinate with metal ion by its terminal and bridge oxygen atoms, but also the number of metal ion combined often changes on a case by case basis as demonstrated in this work. With the introduction of the transition-metal complexes (TMCs), molybdenum arsenate fragments acting as unusual inorganic ligands can multiply bind several TMCs through terminal or bridge oxygen atoms [12,13].As a part of our effort in the hydrothermal assembly of new solid materials [14,15], we try to find the rational reaction condition to obtain new material based on inorganic molybdenum arsenate building units with novel structures and interested properties and then further investigate their final applications in material science. Herein, we report the syntheses and structural characterization of a new molybdenum arsenate compound [{Cu(imi) 2 } 3 As 3 -Mo 3 O 15 ] Á H 2 O.…”

“…As a part of our effort in the hydrothermal assembly of new solid materials [14,15], we try to find the rational reaction condition to obtain new material based on inorganic molybdenum arsenate building units with novel structures and interested properties and then further investigate their final applications in material science. Herein, we report the syntheses and structural characterization of a new molybdenum arsenate compound [{Cu(imi) 2 2 ] complexes belong to a MoO 6 octahedron with little steric crowding.…”