“…Solution-processable organic photodetectors (OPDs) have attracted interest because of their potential to replace conventional inorganic semiconductor-based photodetectors (PDs) and fabricate low-cost flexible image sensors. − Particularly, near-infrared (NIR) OPDs responding to approximately 750–1400 nm light are of great interest due to potential applications in optical communication, night vision, light detection and ranging (LiDAR), and health-monitoring devices. − The spectral range of NIR light absorption has been substantially extended through device architecture optimization , and the development of low-bandgap ( E g ) conjugated organic molecules (COMs) − or conjugated polymers (CPs). − However, the successful demonstration of NIR OPDs still faces a major challenge in developing high NIR-photon-to-electron conversion efficiency at λ > 900 nm, which is the desired wavelength for operating NIR devices, including LiDAR systems . Furthermore, as E g decreases for NIR light-absorbing materials, the dark current increases, significantly reducing OPD performance (such as low detectivity). ,,, Thus, organic materials with both high absorption coefficients at >900 nm and low dark current for practical NIR OPD applications should be developed.…”