A 3D porous zinc MOF constructed from a flexible tripodal ligand: Synthesis, structure, and photoluminescence property

A high connectivity metal–organic framework with exceptional hydrogen and methane uptake capacities

“…To our knowledge, the 6,8-connected 2-nodal nets are still very rare for MOF materials. 44,45 Furthermore, only the sea topology has been reported for these MOFs 46 among the four (6,8)-connected 3D network topologies listed in the RCSR database (ocu, sea, seh, and tph). 47 2 thus represents the first example of MOFs with the tph network topology.…”

Aqueous room temperature synthesis of zeolitic imidazole framework 8 (ZIF-8) with various concentrations of triethylamine

“…[6][7][8][10][11][12][13] A common synthesis method consists of mixing a highly diluted metal salt and organic ligands in an organic solvent and heating them in an autoclave at temperatures up to 200 C. Despite its prevalence, this approach is time-consuming and requires high energy consumption. 1,14 The microwave-assisted solvothermal method is less time-consuming compared to the solvothermal process, 15 and both solvothermal and microwave-assisted synthesis processes have their own advantages and limitations. Although better yield and smaller particle size can be obtained through microwave-assisted synthesis, the process requires unfavorably high energy.…”

Determination of heat capacities and thermodynamic properties of two structurally unrelated but isotypic calcium and manganese(II) 2,6-naphthalene dicarboxylate-based MOFs

“…Metal-organic frameworks (MOFs) are molecular architectures comprising metal ion nodes bridged by organic ligands, which have attracted much interest recently due to their potential interest for gas storage [1][2][3][4][5], gas separation [6][7][8][9][10], as catalytic active phases [11][12][13][14][15], and as luminescent materials [16][17][18]. Among the numerous synthetic routes leading to MOF materials, most of them involve the use of metal carboxylates as organic ligands that readily interact with various metal ions through their negatively charged ends.…”