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Schuurman, Y.; Mirodatos, C.; Ferreira-Aparicio, Paloma; Rodrı́guez-Ramos, I.; Guerrero-Ruı́z, A.

doi:10.1023/a:1019022917507

Cited by 34 publications

(14 citation statements)

References 27 publications

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“…PGMs, including Ru, Rh, Ir, Pt and Pd, have been identified as excellent reforming catalysts for MDR 29,31,36,[40][41][42][43][44]63,[67][68][69]75,76 and MSR. 56,60,[64][65][66][77][78][79][80][81] The use of PGMs for CH 4 conversion is relevant in the context of partial oxidation and dry reforming, for which the use of Ni is excluded (because of oxidation and severe coking).…”

Section: Platinum Group Metalsmentioning

confidence: 99%

Solar thermal catalytic reforming of natural gas: a review on chemistry, catalysis and system design

Simakov

Wright

Ahmed

et al. 2015

Catal. Sci. Technol.

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Section: Platinum Group Metalsmentioning

confidence: 99%

Solar thermal catalytic reforming of natural gas: a review on chemistry, catalysis and system design

Simakov

Wright

Ahmed

et al. 2015

Catal. Sci. Technol.

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“…The TAP technique has been applied to different reaction systems involving heterogeneous catalysis: Reaction transport (adsorption and diffusion) [44,45]; reforming of hydrocarbons [46][47][48][49][50][51]; hydrogenation and dehydrogenation reactions [52,53]; environmental catalysis [54][55][56][57][58]; oxidation reactions etc. [59][60][61][62][63][64][65][66][67].…”

Section: Approaches Of Kinetic Analysis For Ftsmentioning

confidence: 99%

Recent Progresses in Understanding of Co-Based Fischer–Tropsch Catalysis by Means of Transient Kinetic Studies and Theoretical Analysis

Yang

Chen

et al. 2014

Catal Lett

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During the last years it has been an increasing focus on fundamental studies of the Fischer-Tropsch synthesis (FTS). Steady-state isotopic transient kinetic analysis and first principles investigation have proven to be important methods in studying the reaction mechanism of FTS. The present contribution deals with recent progresses in understanding of the F-T mechanism on Co catalysts based on combined DFT calculations, in situ characterization, steady-state isotopic transient kinetic analysis and microkinetics. A brief outlook into future perspectives of the FTS for converting synthesis gas from different carbon sources to fuels and chemicals is also provided.

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“…15 DRM, reforming of CH 4 using CO 2 , produces high purity syngas containing little CO 2 , with H 2 /CO ratio r 1 16,17 but is highly endothermic. One example of its use in sustainable energy production is in solar-chemical energy transmission systems, [18][19][20][21] where the heat from the renewable resources like the sun can be used to drive the endothermic reaction forward.…”

Section: Introductionmentioning

confidence: 99%

A review of dry (CO₂) reforming of methane over noble metal catalysts

2014

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Dry (CO2) reforming of methane (DRM) is a well-studied reaction that is of both scientific and industrial importance. This reaction produces syngas that can be used to produce a wide range of products, such as higher alkanes and oxygenates by means of Fischer-Tropsch synthesis. DRM is inevitably accompanied by deactivation due to carbon deposition. DRM is also a highly endothermic reaction and requires operating temperatures of 800-1000 °C to attain high equilibrium conversion of CH4 and CO2 to H2 and CO and to minimize the thermodynamic driving force for carbon deposition. The most widely used catalysts for DRM are based on Ni. However, many of these catalysts undergo severe deactivation due to carbon deposition. Noble metals have also been studied and are typically found to be much more resistant to carbon deposition than Ni catalysts, but are generally uneconomical. Noble metals can also be used to promote the Ni catalysts in order to increase their resistance to deactivation. In order to design catalysts that minimize deactivation, it is necessary to understand the elementary steps involved in the activation and conversion of CH4 and CO2. This review will cover DRM literature for catalysts based on Rh, Ru, Pt, and Pd metals. This includes the effect of these noble metals on the kinetics, mechanism and deactivation of these catalysts.

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Untitled

Cited by 34 publications

References 27 publications

Solar thermal catalytic reforming of natural gas: a review on chemistry, catalysis and system design

Solar thermal catalytic reforming of natural gas: a review on chemistry, catalysis and system design

Recent Progresses in Understanding of Co-Based Fischer–Tropsch Catalysis by Means of Transient Kinetic Studies and Theoretical Analysis

A review of dry (CO₂) reforming of methane over noble metal catalysts

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Untitled

Cited by 34 publications

References 27 publications

Solar thermal catalytic reforming of natural gas: a review on chemistry, catalysis and system design

Solar thermal catalytic reforming of natural gas: a review on chemistry, catalysis and system design

Recent Progresses in Understanding of Co-Based Fischer–Tropsch Catalysis by Means of Transient Kinetic Studies and Theoretical Analysis

A review of dry (CO2) reforming of methane over noble metal catalysts

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A review of dry (CO₂) reforming of methane over noble metal catalysts