3D-Printed Hierarchically Micro–Nano-structured NiFe Catalysts for the Stable and Efficient Oxygen Evolution Reaction

Abstract

The high overpotential of the oxygen evolution reaction (OER) is the main obstacle to water electrolysis for green hydrogen production. NiFe-based materials are the potential non-precious metal electrocatalysts for the OER, but their poor stability and limited activity have been of concern. Herein, a three-dimensional self-supporting NiFe electrode is prepared by direct writing 3D printing using spherical powders of Ni and Fe metals followed by hydrothermal treatment at 130 °C in urea and NH4F mixed solution. The fabricated 3D micro–nano-structured NiFe electrode presents an excellent OER activity of 220 mV overpotential to reach 100 mA cm–2 with a Tafel slope of 49.1 mV dec–1 and stability up to 100 h in continuous or intermittent power supply. The hydrothermal treatment produces in situ growth of flower-like clusters of NiFe2O4 nanoneedles wrapped with FeOOH nanosheets on the surface of the 3D NiFe bimetal microsphere network, and the outstanding OER activity is attributed to a wide variety of interfaces and heterojunctions among metal microspheres, metal oxides, and hydroxides. This study provides an approach for preparing high-performance self-supporting electrodes for electrochemical processes.

S-Doped Ni0.5Co0.5Fe2O4 Porous Single-Crystalline Nanosheets for Electrocatalytic Oxygen Evolution

“…Current research focuses on non-precious metal compounds, such as Fe, Ni, Co, and Mn-based oxides, sulfides, and hydroxides. − Some of these compounds are indeed prospective catalysts to activate OER. For instance, Co- and Fe-based oxides are stable in alkaline media; their OER properties are not so much different from those of Ru and Ir oxides. , In particular, spinel type oxides (general formula AB 2 O 4 ) have been accepted as promising OER catalysts owing to their multiple valence of cations and their ability to transform between different oxidation states. − Among spinel oxide structures, spinel ferrite (MFe 2 O 4 , M = Co, Ni, Mn, etc.)…”

Convenient Synthesis of NiCo Alloy Nanoparticles Encapsulated by N-Doped Porous Carbon for the Oxygen Evolution Reaction

“…They employed a unique methodology that involved a 3D printing technique following a hydrothermal process. This was executed utilizing spherical powders of Ni and Fe as the foundational materials . The engineered NiFe electrode, featuring a distinctive three-dimensional microarchitecture, exhibited an overpotential of a mere 220 mV while achieving a catalytic current density measuring 100 mA cm –2 .…”