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Miyatani, Rie; Amao, Yutaka

doi:10.1023/a:1020912527723

Cited by 75 publications

(25 citation statements)

References 8 publications

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“…Reductive action of a formate dehydrogenase (FDH) on CO 2 is a potential strategy for production of formate, however most FDHs show a strong preference for catalyzing the reverse reaction (i.e., formate oxidation). [1][2][3][4][5][6] Against this background, FDHs from a variety of organisms were investigated as potential industrial biotransformation catalysts.…”

Section: Formate Production Through Biocatalysismentioning

confidence: 99%

Formate production through biocatalysis

2013

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Section: Formate Production Through Biocatalysismentioning

confidence: 99%

Formate production through biocatalysis

2013

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“…[98][99][100] ZnTMPyP 4 + has been used as a photosensitizer, as shown in Scheme 17. Next, the synthesis of formic acid from HCO 3 À with FDH and the photoreduction of MV 2 + with systems using water soluble zinc porphyrins have been introduced.…”

Section: Artificial Photosynthesis System For Solar Fuel Production Fmentioning

confidence: 99%

Solar Fuel Production Based on the Artificial Photosynthesis System

Amao¹

2011

ChemCatChem

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111

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ChemCatChem 2011, 3, 458 -474 through water photolysis and those that produce methanol by CO 2 reduction with the aid of an artificial photosynthesis system. As hydrogen and methanol are low-carbon fuels (the emission of CO 2 from the combustion of these fuels is low), they are considered to be alternatives to fossil resources. In this review, solar fuel production systems consisting of an artificial photosynthesis system, a catalyst, and an enzyme are discussed. These systems are expected to help in reducing CO 2 and to promote the use of low-carbon fuels in the future. Scheme 1. Z Scheme of the natural photosynthesis of higher green plants and oxygenic photosynthetic cyanobacteria.[a] Dr.Scheme 2. Solar hydrogen production or CO 2 photoreduction to low carbon fuels, such as formic acid and methanol by using PSI and PSII in the presence of suitable catalyst.Scheme 3. Artificial photosynthesis system for solar hydrogen production or CO 2 photoreduction to low carbon fuels, such as formic acid and methanol.Scheme 4. Artificial photosynthesis system with visible light irradiation consisting of an electron donor (ED), a photosensitizer (S1), and an electron relay (EC1). 460 www.chemcatchem.org

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“…For photoinduced hydrogen production systems, platinum nano-particle and enzyme, hydrogenase from Desulfovibrio vulgaris (Miyazaki) have been widely used as catalysts [6][7][8][9][10]. The photochemical and enzymatic synthesis of organic compounds has also been developed using this system in the presence of various enzymes [11][12][13][14][15][16][17][18][19][20][21][22]. Dehydrogenase enzymes such as lactate (LDH), formate (FDH), aldehyde (AldDH) and alcohol dehydrogenase (ADH) are useful enzymes for the synthesis of valuable organic compounds such as lactic acid, formic acid, methanol etc.…”

Section: Introductionmentioning

confidence: 99%