37‐3: Late‐News Paper: Achieving High Field‐Effect Mobility Exceeding 60 cm²/Vs in IZTO Transistor via Metal‐Assisted Crystallization

Abstract

In this paper, the effects of post annealing on the structural, chemical and electrical properties of tantalum (Ta) capped IZTO films were examined for use as the channel in thin-film transistors (TFTs). The onset crystallization temperature of amorphous IZTO was found to be  700 C, which is not suitable for glass or plastic substrate-based display devices. New crystallization method involving the catalytic Ta capping and subsequent post annealing was proposed for the IZTO material system at a low temperature of 200 C. The TFTs with Ta-assisted crystallized IZTO channel exhibited a high field-effect mobility of 60.3 cm 2 /Vs, subthreshold swing of 0.20 V/decade, threshold voltage of -0.39 V, and ION/OFF ratio of ~10 8 , which was superior to the control device without Ta-assisted crystallization. The reason for this high performance is discussed on basis of the lattice ordering and chemical purification of IZTO channel layer. Existence of two dimensional grain boundary defects as a crystallization of IZTO channel layer was found to hardly affectthe charge carrier transport, suggesting that they are electrically inactive.

P‐4: Novel Oxide Semiconductors Enabling as High On‐State Current as LTPS

“…Ito et al recently reported high-mobility IGZO with a Hall mobility of 50 cm 2 /Vs [8]. Other highmobility materials, such as indium-tungsten oxide (IWO), indium-zinc-tin oxide (IZTO), and indium-gallium-zinc-tin oxide (IGZTO), were also reported [9][10][11].…”