236. Mechanism of substitution at a saturated carbon atom. Part LIV. Kinetics of chlorine exchange between triphenylmethyl chloride and tetra-n-butylammonium chloride in benzene
Abstract:The kinetics are studied of the exchange of chlorine between triphenylmethyl chloride and tetra+butylammonium radiochloride in benzene at
26-46O.In these conditions the reaction is of first order in triphenylmethyl chloride, and of zeroth order in the salt at all concentrations up to saturation.This kinetic form and rate are practically unaffected by added tetra-nbutylammonium perchlorate, which undergoes no stoicheiometric reaction with triphenylmethyl chloride. But the kinetic form is changed, and the initia… Show more
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