2013
DOI: 10.1002/adma.201204407
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Highly Pure Solid‐State White‐Light Emission from Solution‐Processable Soft‐Hybrids

Abstract: Highly pure and solution processable white-light-emitting hybrids are presented. These soft-hybrids are designed by an organic-inorganic supramolecular co-assembly in water. White-light emission is achieved by partial energy transfer (ET) between donor and acceptor molecules anchored on the inorganic component. The unique and remarkable processability feature of these hybrids is demonstrated by painting/writing onto large glass and flexible plastic substrates.

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Cited by 138 publications
(96 citation statements)
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“…[64,65] Although not fabricated as WLEDs, white light-emitting soft hybrids was reported based on the supramolecular co-assembly of organoclays and ionic chromophores. [66][67][68] Layered magnesium phyllo(organo)silicate was used as the inorganic counterpart, while coronene tetra-carboxylate (CS), sulforhodamine G (SRG), and tetraphenylethylene derivatives (TPTS) were employed as donor-acceptor chromophores (Figure 4).…”
Section: White Light Emission and Ledsmentioning
confidence: 99%
“…[64,65] Although not fabricated as WLEDs, white light-emitting soft hybrids was reported based on the supramolecular co-assembly of organoclays and ionic chromophores. [66][67][68] Layered magnesium phyllo(organo)silicate was used as the inorganic counterpart, while coronene tetra-carboxylate (CS), sulforhodamine G (SRG), and tetraphenylethylene derivatives (TPTS) were employed as donor-acceptor chromophores (Figure 4).…”
Section: White Light Emission and Ledsmentioning
confidence: 99%
“…We recently reported a novel method to prepare luminescent LnNCs by simply mixing deprotonated aromatic carboxylic acid, Ln 3+ ions, and aminoclay (AC, a layered magnesium phyllosilicate [19,20]) in aqueous solution [21,22]. The negatively charged carboxylate groups are expected to interact electrostatically with the positively charged AC units and can coordinate with Ln 3+ (Ln=Eu and/or Tb) in aqueous solution, resulting in hydrophilic noncovalent hybrid composites with tunable emission colors.…”
Section: Introductionmentioning
confidence: 99%
“…For decades, many solid state materials have been explored and developed as white light emitting sources. These include inorganic oxide, inorganic quantum dots, nitride, organic molecules, polymers, and metal complexes [4][5][6][7][8][9][10][11][12]. Common approaches, such as dichromatic, tri-chromatic, and tetra-chromatic methods are often used to generate white light [13][14][15].…”
Section: Introductionmentioning
confidence: 99%