2,4,6‐Triphenylphenoxyl

Abstract

2,4,6‐Triphenylphenoxyl intermediate: 2,4,6‐triphenylaniline intermediate: 2,4,6‐triphenylphenol product: 2,4,6‐triphenylphenoxyl

Iron salt-promoted oxidation of steroidal phenols by m-chloroperbenzoic acid: a route to possible antitumor agents

“…13,14 Oxidation of several phenol ethers with DAIB and PIFA was used for the synthesis of a series of antitumor quinols. 15 It was also known that phenols can be oxidized by various oxidants in the presence of Fe(II) 16 and Fe(III) 17 salts, usually via intermediate phenoxy radical. 18 As assumed, the neuroprotective role of phenols in living cells is accomplished by oxidative quenching of hydroxyl radicals, products of ferricassisted degradation of hydroperoxides in cytochrome P450.…”