©Operative Dentistry, 2007, 32-2, 160-165
LES Soares • PCS Liporoni • AA Martin
Clinical RelevancePhoto-polymerization using second generation LED and halogen light in the soft-start mode of curing was able to produce an adequate degree of conversion in resin composites. The lower degree of conversion produced by low power LED in the soft-start mode could lead to restoration failure, degradation of the organic matrix and recurrent caries.
SUMMARYFourier-Transform (FT)-Raman spectroscopy was used to evaluate in vitro the degree of conversion (DC) of Charisma dental composite cured by three different light curing units (LCUs) using soft-start and normal protocols. Eighty circular blocks of resin (7 mm in diameter x 2.5 mm thick) were prepared and cured using the following sources: halogen light (Degulux soft-start, n=20, G1-G2), low power light emitting diode (LED) with transparent polymer tip (LD13, n=20, G3-G4) and fiber optic tip (LD13, n=20, G5-G6) and, finally, high power LED (Radii, n=20, G7-G8). The top and bottom surfaces of the blocks were analyzed by FT-Raman spectroscopy. The respective DCs were estimated calculating the peak height ratio of the aliphatic C=C (1640 cm -1 ) and aromatic C=C (1610 cm -1 ) Raman modes. The DC at the surfaces ranged between 50% and 60% for the top and 46% and 58% for the bottom. The halogen light and high power LED LCUs with the soft-start and normal protocols produced the highest DC values of dental composite at both surfaces (p<0.001). Curing by low power LED in the soft-start protocol did not produce adequate DC at the depth of 2.5 mm. The type of LCU light guide tip did not present a significant statistical difference in the final DC of the dental composite (p>0.05).