Solid particles were delivered to the reactor from a hopper consisting of a 4" diameter acrylic tube. Particles were metered with a ¼" diameter auger running axially through the hopper to an exit tube attached to flexible tubing that connected to the top of the reactor. The entrance point of the auger to the hopper was sealed using a 3/8" fitting sealed with an o-ring, and the turning rate was maintained at 3-70 rpm using a variable speed mixer motor. Solid particles were agitated to sufficiently fill the auger by impact of a plastic tube fastened to the front of a 10" subwoofer operating at 30 Hz. The top of the reactor consisted of an annulus of 7 mm OD through which solid particles and air flowed down to the front face of the catalyst foam bed.Gases were metered using mass flow controllers for N 2 , O 2 , and CH 4 at startup.
Supplemental Information: Reactor SetupThe reactor tube consisted of an 18-mm-i.d., ca. 55-cm-long quartz tube. The metal catalysts were loaded on a ceramic foam or sphere fixed bed by the wet impregnation technique described previously.[ The catalyst was initially heated by methane partial oxidation to 800 °C after which a continuous flow of solid particles was immediately applied to the front catalyst surface.Methane was removed from the system and the flow rate of air was adjusted to satisfy 0.6 < C/O < 1.0. No external heating was required as solid particles and air entered the reactor at room temperature. The quartz reactor tube was wrapped in 1 in. of insulation to prevent radial heat