Hydration properties of Al3+ ion using empirical ion-water potential by Monte Carlo simulation

Adaptable DNA-Interactive Probe Proficient at Selective Turn-On Sensing for Al3+: Insight from the Crystal Structure, Photophysical Studies, and Molecular Logic Gate

“…This distinctive selectivity of the probe toward Al 3+ could be inferred in terms of the higher charge density and smaller ionic radius of the Al 3+ . 18 , 31 , 32 The molecule was nearly nonemissive due to the photoinduced electron transfer (PET) effect from an aldamine N-atom and the ESIPT process operating simultaneously.…”

“…Thus, the selective detection of the potent analyte Al 3+ in various samples before entering in the human body has been of great importance. However, the sensing of Al 3+ has been restricted due to its strong hydration enthalpy in the aqueous environment and poor coordination ability. , On addition, the complex level of synthesis and purity are active in developing highly selective and sensitive chemosensors for Al 3+ ions limiting its practical utility. Therefore, developing fluorescent probes that are easy to synthesize and show excellent selectivity toward Al 3+ ions is very much desired.…”

PDMPO: a specific silicon or silica, pH sensitive fluorescent probe?

“…19 At pH 7 and 9, it is the hydroxylated Al(OH) 4 À whose rst coordination shell is tetrahedral. 20 The particle size distribution in the PDMPO-Al system (Fig. 7) is like that of the PDMPO alone and different from that of the PDMPO-Si system, which would conrm a different bond type and location on PDMPO.…”

“…Aluminosilicate species and oligomers can form before suspended particles are visible in the solution. 20 The observed dispersion of the uorescence intensity measurements can be related to uncontrolled kinetics of mineral particles precipitation. The particle size distribution (Fig.…”

Aqueous rocking-chair aluminum-ion capacitors enabled by a self-adaptive electrochemical pore-structure remolding approach

“…An effective method to screen the electric field around bare ions is to introduce solvent shells around them, i.e., employing solvated Al 3+ ions as the charge carriers. 14 In this case, the charge storage mechanism of the corresponding EES device will change to a fast capacitive process. [15][16][17] The capacitive charge storage mechanism provides EES devices with outstanding cycle stability, high energy efficiency, and excellent rate and power performances, but meanwhile might have a negative impact on their energy density.…”