Effects of Hydrogen in Stress Triaxiality of API 5L X70 Steel

Abstract

Hydrogen embrittlement (HE) in API 5L X70 steel was investigated by testing notched and unnotched uniaxial tensile specimens and single-edge tension specimen, SE(T). Apparent hydrogen diffusivity (D app = 1.4 x 10 -10 m 2 /s) and solubility (S app = 4.9 mol H/m 3 ) were determined by electrochemical hydrogen permeation tests. Through mathematical fitting, it was possible to separate the strong traps present at the beginning of the first permeation curve (φ = 0.43 mol H/m 3 ). Uniaxial tensile tests showed a loss of ductility of up to 33% in the hydrogenated condition. Fracture mechanics tests exhibited a toughness decrease of 14% after exposure to hydrogen. The high resistance to HE was presented suggesting that these microalloyed steels can solubilize hydrogen in the matrix with low segregation, reducing the impact on embrittlement. A mix of ductile and quasi-cleavage fracture was observed in the hydrogenated samples with an increased stress triaxiality.