“…Aliphatic diamines, which are starting compounds for polyamides, are widely used in textile and machine engineering and are therefore among the most commercially available bridging ligands can be used to form coordination polymers [28][29][30][31][32][33][34][35][36]. Metal complexes with aliphatic diamines are particularly interesting for studying their structure in crystals [30,[32][33][34][36][37][38][39][40], developing bistable systems [19,28,29,41,42], and creating materials with almost zero thermal expansion effect [35].…”