1993
DOI: 10.1016/0009-2614(93)87242-u
|View full text |Cite
|
Sign up to set email alerts
|

1,3-hydrogen shift in phosphapropenes. Suprafacial sigmatropic rearrangements

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
1
1

Citation Types

0
5
0
1

Year Published

1999
1999
2019
2019

Publication Types

Select...
6
1

Relationship

0
7

Authors

Journals

citations
Cited by 12 publications
(6 citation statements)
references
References 12 publications
0
5
0
1
Order By: Relevance
“…[41] This thermal isomerization has been studied from a theoretical standpoint. [42] Unlike the corresponding allcarbon systems, a concerted suprafacial [1,3] sigmatropic shift of the hydrogen atom seems to be possible.…”
Section: F Matheymentioning
confidence: 91%
“…[41] This thermal isomerization has been studied from a theoretical standpoint. [42] Unlike the corresponding allcarbon systems, a concerted suprafacial [1,3] sigmatropic shift of the hydrogen atom seems to be possible.…”
Section: F Matheymentioning
confidence: 91%
“…(12) ] 41. Einer theoretischen Untersuchung42 dieser thermischen Isomerisierung zufolge kann anders als bei den analogen reinen Kohlenstoffverbindungen eine konzertierte suprafaciale [1,3]‐sigmatrope Verschiebung des Wasserstoffatoms stattfinden.…”
Section: Phosphaalkeneunclassified
“…Although there is no definitive experimental evidence for a thermal, concerted [1,3]hydrogen shift in a hydrocarbon system, this possibility has been already pointed out for related systems such as alkyl-substituted allenes, 1-silapropene, and 1-phosphapropene. [10][11][12][13][14] The benchmark [1 s ,3 a ] rearrangement of hydrogen in the allyl system (propene) has been extensively studied from a theoretical viewpoint. [15][16][17][18][19][20][21][22][23][24] The interest has been mainly devoted to the elucidation and understanding of structural, dynamical, and thermodynamical aspects of such fundamental pericyclic chemical processes.…”
Section: Introductionmentioning
confidence: 99%
“…Particularly interesting are the unimolecular and one step [1,3] sigmatropic rearrangements because of their relevant applications in organic and inorganic synthetic chemistry. Although there is no definitive experimental evidence for a thermal, concerted [1,3]hydrogen shift in a hydrocarbon system, this possibility has been already pointed out for related systems such as alkyl-substituted allenes, 1-silapropene, and 1-phosphapropene. The benchmark [1 s ,3 a ] rearrangement of hydrogen in the allyl system (propene) has been extensively studied from a theoretical viewpoint. The interest has been mainly devoted to the elucidation and understanding of structural, dynamical, and thermodynamical aspects of such fundamental pericyclic chemical processes. Results, based on several types of calculations, have been finally interpreted in terms of the simple theoretical principles of the Woodward−Hoffmann rules for the conservation of orbital symmetry.…”
Section: Introductionmentioning
confidence: 99%