Untitled

Kazankova, M. A.; Efimova, I. V.; Kochetkov, A. N.; Afanas'ev, V.V.; Beletskaya, I. P.

doi:10.1023/a:1022548303903

Cited by 32 publications

(13 citation statements)

References 27 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In the presence of palladium(0) and nickel(0) complexes the β-adduct 127a was formed as the major product. By contrast palladium(II) and nickel(II) complexes mainly gave rise to the α-adduct 126a [ 98 , 238 ]. The nickel based catalyst was more effective than the palladium so the reaction proceeded at lower temperature.…”

Section: Reviewmentioning

confidence: 99%

Preparation of phosphines through C–P bond formation

Wauters¹,

Debrouwer²,

Stevens³

2014

Beilstein J. Org. Chem.

170

View full text Add to dashboard Cite

show abstract

Section: Reviewmentioning

confidence: 99%

Preparation of phosphines through C–P bond formation

Wauters¹,

Debrouwer²,

Stevens³

2014

Beilstein J. Org. Chem.

170

View full text Add to dashboard Cite

show abstract

“…In the presence of Pd(0) and Ni(0) complexes, the β-adduct was formed as the major product. By contrast, Pd(II) and Ni(II) complexes mainly gave rise to the α-adduct (α:β = 95:5) [58]. The different selectivity in the reactions catalyzed by Pd(0)/Ni(0) complexes and Pd(Ni)X 2 is explained by the formation of catalytic amounts of HX (HOAc or HBr) in situ, which initiate the second catalytic cycle.…”

Section: Hydrophosphination Reactions Of Alkenes and Alkynesmentioning

confidence: 97%

Nickel Complexes in C‒P Bond Formation

et al. 2021

View full text Add to dashboard Cite

This review is a comprehensive account of reactions with the participation of nickel complexes that result in the formation of carbon–phosphorus (C‒P) bonds. The catalytic and non-catalytic reactions with the participation of nickel complexes as the catalysts and the reagents are described. The various classes of starting compounds and the products formed are discussed individually. The several putative mechanisms of the nickel catalysed reactions are also included, thereby providing insights into both the synthetic and the mechanistic aspects of this phosphorus chemistry.

show abstract

“…An effective palladium‐catalyzed addition of diphenylphosphine to alkynes was reported [44] . The optimized reaction conditions for the Pd‐catalyzed addition of diphenylphosphine to alkynes was Pd(PPh 3 ) 4 (2 mol %) in acetonitrile solvent at 130 °C.…”

Section: Phosphorus Coupling Partnersmentioning

confidence: 99%

Palladium‐ Catalyzed C−P Bond Forming Reactions: An Overview

Kanchana¹,

Diana²,

Mathew³

et al. 2021

ChemistrySelect

View full text Add to dashboard Cite

Transition metal catalyzed synthesis of organo‐phosphorus compounds show rapid advances. Due to the powerful bond‐forming ability under mild reaction conditions and wide functional group tolerance made palladium‐catalyzed reactions an inevitable tool for the synthesis of various structurally diversed complex molecules. This review is an account of palladium‐catalyzed Carbon‐Phosphorous bond forming reactions. For proving an insight into the synthetic and mechanistic knowledge of its chemistry some of the mechanisms of this type of catalysis are also added. This review focuses on the recent advances in Palladium‐catalyzed C−P bond forming reactions and covers literature from 2001 to 2020.

show abstract

Untitled

Cited by 32 publications

References 27 publications

Preparation of phosphines through C–P bond formation

Preparation of phosphines through C–P bond formation

Nickel Complexes in C‒P Bond Formation

Palladium‐ Catalyzed C−P Bond Forming Reactions: An Overview

Contact Info

Product

Resources

About