The Tomtor massif of Paleozoic ultramafic alkaline rocks and carbonatites is located in the northern part of the Sakha Republic (Yakutia). The massif (its total area is ~250 km 2 ) is ~20 km in diameter, with a rounded shape and a concentrically zoned structure. The core of the massif consists of carbonatites surrounded by a discontinuous ring of ultramafic rocks and foidolites. The outer part is composed of alkali and nepheline syenites. All rocks are weathered and covered with eluvium, which is the thickest after carbonatites enriched in phosphates and REE. The weathering profile consists of four layers, from the top: kaolinite-crandallite, siderite, goethite, and francolite. The highest-grade ores are observed in the bedded deposit which fills depressions in "sagging" eluvium. The ores are laminated and cryptogranular, with high Nb, Y, Sc, and REE contents (on average, 4.5% Nb 2 O 5 , 7-10% REE 2 O 3 , 0.75% Y 2 O 3 , and 0.06% Sc 2 O 3 ). The highest-grade ores are natural Nb and REE concentrates. The total REE content in some layers is >10%. The morphologic features of the highest-grade phosphate ores from the northern part of the Burannyi site were studied. The ore-forming minerals belong to the pyrochlore group, crandallite group (goyazite), and monazite-Ce. The pyrochlore group minerals occur mainly as crystals that were completely replaced by barium-strontium pyrochlore and/or plumbopyrochlore but retained the original faces; also, they occur as numerous conchoidal fragments. The grains of the pyrochlore group minerals sometimes have a zonal structure, with an unaltered pyrochlore core and a reaction rim. Goyazite occurs predominantly as colloform grains. According to SEM and TEM data, monazite occurs in the ores as ~50 nm particles, which cover the outer part of halloysite tubes (800-3000 nm long and 300 nm in diameter) as a dense layer and make up peculiar biomorphic aggregates. The mineralogical data, the occurrence of biomorphic aggregates, and the close association of organic remains with ore minerals suggest that the high-grade ores of the Tomtor deposit, including the Burannyi site, resulted from a hydrothermal-sedimentary process with a presumably important role of bioaccumulation of REE phosphates.

Four stages of the thermochemical plume—lithosphere interaction generating a broad mushroom-like head of plume and especially fourth regressive cooling phase have the important role for metallogeny. The analysis of a thermochemical plume model together with recent geological and geochronological data on magmatic ore systems in the Siberian, Tarim, Emeishan, Central European, and some other large igneous provinces (LIPs) enabled the following characteristics of the metallogeny in large igneous provinces to be revealed: (1) the specific combination of mineralization types, which include magmatic Cu-Ni-Pt and Fe-Pt; hydrothermal Ni-Co-As (±Ag, U, Au), Au-As, Ag-Sb, Au-Hg, Sb-Hg and stratiform Cu (copper-bearing sandstones and shales enriched in Co, Ni, Ag, Pt);(2) the areal or spot-like pattern of the location of mineralization types (opposed to the linear-belt localization in subduction and rift settings);(3) the zoned distribution of mineralization types relative to LIPs’ centers, with Cu-Ni-Pt, Fe-Pt and stratiform Cu mineralization localized in a LIP center, and hydrothermal mineralization bound to a LIP periphery;(4) the essential contemporaneity of the formation of each mineralization type in LIPs, and the existence of coeval but spatially separated Cu-Ni-Pt, Ni-Co-As and Au-As deposits;(5) the close linkage between different mineralization types and particular pulses of mafic, alkaline mafic, and felsic magmatism;(6) the unified succession of ore-forming events;(7) the close relationship between the extent of mineralization and LIP igneous volumes, which in turn depend on the plume heat power. The major characteristics of localization of different mineralization types within LIPs, the timing and genetic relationships between mineralization and types of magmatism, as well as specific geological controls on ore formation provide a basis for establishing new geological, magmatic, litological, and geochemical criteria crucial for predicting and targeting new mineralization within LIPs.

We report new isotope dates and metallogenic and chemical characteristics of granitoids from the Hangayn area (central Mongolia) with implications for the time and tectonic settings of their formation. Proximal U-Pb and Ar-Ar ages of 241.3±1.5 Ma and 238.2±2.5 Ma have been obtained for the Triassic Guchin Us and Hurmen Gol intrusions, respectively, and an Early Permian age (288.7±2.3 Ma, Ar-Ar) for the Bayanulaan granite and for granite porphyry from the Saran Uul Cu-Mo-(Au) deposit. Granitoids of the Egiyn Davaa, Hangayn, and Shar Us Gol complexes in the southwestern Hangayn area are of two geochemical types. Some intrusions that were formerly attributed to these complexes have been reinterpreted as resulting from multiple plutonic pulses of different ages. According to our new data and published evidence, most of granitoids in the area may have been produced by Early-Middle Triassic (255–230 Ma) rather than Permian and Late Triassic-Early Jurassic events. The Hangayn granitoids are of low mineral potential. Gold mineralization in the area is confined within the Hangayn gold belt and appears to be independent of the intrusions.

BackgroundGeothermal areas are of great interest for the study of microbial communities. The results of such investigations can be used in a variety of fields (ecology, microbiology, medicine) to answer fundamental questions, as well as those with practical benefits. Uzon caldera is located in the Uzon-Geyser depression that is situated in the centre of the Karym-Semyachin region of the East Kamchatka graben-synclinorium. The microbial communities of Zavarzin spring are well studied; however, its benthic microbial mat has not been previously described.ResultsPyrosequencing of the V3 region of the 16S rRNA gene was used to study the benthic microbial community of the Zavarzin thermal spring (Uzon Caldera, Kamchatka). The community is dominated by bacteria (>95% of all sequences), including thermophilic, chemoorganotrophic Caldiserica (33.0%) and Dictyoglomi (24.8%). The benthic community and the previously examined planktonic community of Zavarzin spring have qualitatively similar, but quantitatively different, compositions.ConclusionsIn this study, we performed a metagenomic analysis of the benthic microbial mat of Zavarzin spring. We compared this benthic community to microbial communities found in the water and of an integral probe consisting of water and bottom sediments. Various phylogenetic groups of microorganisms, including potentially new ones, represent the full-fledged trophic system of Zavarzin. A thorough geochemical study of the spring was performed.

We present new whole-rock major and trace element, mineral chemistry, and U-Pb isotope data for the Ulan-Sar’dag mélange, including different lithostratigraphic units: Ophiolitic, mafic rocks and metavolcanites. The Ulan-Sar’dag mélange comprises of a seafloor and island-arc system of remnants of the Paleo-Asian ocean. Detailed studies on the magmatic rocks led to the discovery of a rock association that possesses differing geochemical signatures within the studied area. The Ulan-Sar’dag mélange includes blocks of mantle peridotite, podiform chromitite, cumulate rocks, deep-water siliceous chert, and metavolcanic rocks of the Ilchir suite. The ophiolitic unit shows overturned pseudostratigraphy. The nappe of mantle tectonites is thrusted over the volcanic-sedimentary sequence of the Ilchir suite. The metavolcanic series consist of basic, intermediate, and alkaline rocks. The mantle peridotite and cumulate rocks formed in a supra-subduction zone environment. The mafic and metavolcanic rocks belong to the following geochemical types: (1) Ensimatic island-arc boninites; (2) island-arc calc-alkaline andesitic basalts, andesites, and dacites; (3) tholeiitic basalts of mid-ocean ridges; and (4) oceanic island basalts. U–Pb dating of zircons from the trachyandesite, belonging to the second geochemical type, yielded a date of 833 ± 4 Ma which is interpreted as the crystallization age during mature island-arc and intra-arc rifting stages. The possible influence of later plume magmatic-hydrothermal activities led to the appearance of moderately alkaline igneous rocks (monzogabbro, trachybasalt, trachyandesite, subalkaline gabbro, and metasomatized peridotites) with a significant subduction geochemical fingerprint.

Data are presented on chromitites from the northern and southern sheets of the Il’chir ophiolite complex (Ospa–Kitoi and Khara-Nur (Kharanur) massifs). The new and published data are used to consider similarities and differences between ore chrome-spinel from the chromitites of the northern and southern ophiolite sheets as well as the species diversity of PGE minerals and the evolution of PGE mineralization. Previously unknown PGE minerals have been found in the studied chromitites. Ore chrome-spinel in the chromitites from the northern sheet occurs in medium- and low-alumina forms, whereas the chromitites from the southern sheet contain only medium-alumina chrome-spinel. The PGE minerals in the chromitites from the southern sheet are Os–Ir–Ru solid solutions as well as sulfides and sulfoarsenides of these metals. The chromitites from the northern sheet contain the same PGE minerals and diverse Rh–Pt–Pd mineralization: Pt–Ir–Ru–Os and isoferroplatinum with Ir and Os–Ir–Ru lamellae. Areas of altered chromitites contain a wide variety of low-temperature secondary PGE minerals: Pt–Cu, Pt–Pd–Cu, PdHg, Rh2SnCu, RhNiAs, PtAs2, and PtSb2. The speciation of the PGE minerals is described along with multiphase intergrowths. The relations of Os–Ir–Ru solid solutions with laurite and irarsite are considered along with the microstructure of irarsite–osarsite–ruarsite solid solutions. Zoned Os–Ir–Ru crystals have been found. Zone Os82–99 in these crystals contains Ni3S2 inclusions, which mark off crystal growth zones. Different sources of PGE mineralization are presumed for the chromitites from the northern and southern sheets. The stages of PGE mineralization have been defined for the chromitites from the Il’chir ophiolite belt. The Pt–Ir–Ru–Os and (Os, Ru)S2 inclusions in Os–Ir–Ru solid solutions might be relics of primitive-mantle PGE minerals. During the partial melting of the upper mantle, Os–Ir–Ru and Pt–Fe solid solutions formed syngenetically with the chromitites. During the late-magmatic stage, Os–Ir–Ru solid solutions were replaced by sulfides and sulfarsenides of these metals. Mantle metasomatism under the effect of reduced mantle fluids was accompanied by PGE remobilization and redeposition with the formation of the following assemblage: garutiite (Ni,Fe,Ir), zaccariniite (RhNiAs), (Ir,Ni,Cu)S3, Pt–Cu, Pt–Cu–Fe–Ni, Cu–Pt–Pd, and Rh–Cu–Sn–Sb. The zoned Os–Ir–Ru crystals in the chromitites from the northern sheet suggest dissolution and redeposition of Os–Ir–Ru primary-mantle solid solutions by bisulfide complexes. Most likely, the PGE remobilization took place during early serpentinization at 450–600 ºC and 13–16 kbar. During the crustal metamorphic stage, tectonic movements (obduction) and a change from reducing to oxidizing conditions were accompanied by the successive transformation of chrome-spinel into ferrichromite–chrome-magnetite with the active participation of a metamorphic fluid enriched in crustal components. The orcelite–maucherite–ferrichromite–sperrylite assemblage formed in epidote-amphibolitic facies settings during this stage. The PGE mineral assemblage reflects different stages in the formation of the chromitites and dunite-harzburgite host rocks and their transformation from primitive mantle to crustal metamorphic processes.

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––Comprehensive studies of structural geology and metallogeny, taking into account the authors’ previous works started as early as the last century, have shown that the southeastern part of East Sayan formed mainly in the Neoproterozoic–early Paleozoic in the settings of multistage thrust and nappe tectonics and tectonomagmatic restructuring of autochthonous and overthrust allochthonous oceanic (ophiolitic), island arc, and ocean-marginal terranes as well as amalgamation of accretion–collision and postcollisional igneous complexes that formed during the opening and subsequent closure of the Paleoasian Ocean marginal structures. In the middle and late Paleozoic, active intraplate volcanic and plutonic processes continued in the thrust/overthrust fault setting, which led to the formation of new dome-shaped nappe structures and the redistribution of ore matter (gold etc.) in large mineral deposits. The final structure of the East Sayan region formed during the late Cenozoic as a result of mountain uplifting and volcanic eruptions, including those in the valley of the Zhombolok River.