The characteristics of the nanosecond overvoltage discharge ignited between semiconductor electrodes based on the CuInSe2 chalcopyrite compound in the argon and nitrogen atmospheres at gas pressures of 5.3–101 kPa are reported. Due to the electrode sputtering, chalcopyrite vapor enters the discharge plasma, so that some CuInSe2 molecules become destroyed, whereas the others become partially deposited in the form of thin films on solid dielectric substrates located near the plasma electrode system. The main products of the chalcopyrite molecule decomposition in the nanosecond overvoltage discharge are determined; these are atoms and singly charged ions of copper and indium in the excited and ionized states. Spectral lines emitted by copper and indium atoms and ions are proposed, which can be used to control the deposition of thin chalcopyrite films in the real-time mode. By numerically solving the Boltzmann kinetic equation for the electron energy distribution function, the electron temperature and density in the discharge, the specific losses of a discharge power for the main electronic processes, and the rate constants of electronic processes, as well as their dependences on the parameter E/N, are calculated for the plasma of vapor-gas mixtures on the basis of nitrogen and chalcopyrite. Thin chalcopyrite films that effectively absorb light in a wide spectral interval (200–800 nm) are synthesized on quartz substrates, by using the gas-discharge method, which opens new prospects for their application in photovoltaic devices.
Curcumin The design of the device for producing a high-current, bipolar nanosecond discharge over the surface of a non-metallic liquid (water, electrolytes, alcohols, etc.) in air is given. Air pressure is ranged from 5 to 101 kPa. The distance between the tip of the blade and the surface of water or liquid (5% solution of copper sulfate in distilled water) was 4 mm, and the distance between parallel metal blades was 40 mm. The conditions for uniform plasma overlapping of the electrolyte surface between the metal blades are established. The spatial, electrical, and optical characteristics of the discharge are investigated. It is shown that the discharge under study allows obtaining colloidal solutions of copper nanoparticles in distilled water in a macroscopic amount (1 liter or more). The developed reactor is of interest for use in poisonous chemical solution disinfection systems, solutions based on dangerous bacteria and viruses for which the use of traditional systems with a point spark discharge or a barrier discharge becomes ineffective. The rector is also promising for the synthesis of colloidal solutions of transition metal oxide nanoparticles from solutions of the corresponding salts. These solutions can be used in micro-nanotechnology and for antibacterial treatment of plants in greenhouses, processing of medical instruments and materials.
The results of experimental study of the characteristics of a two wave UV-VUV lamp on a mixture of argon and freon vapors (CCl 4 ) with pumping by a nanosecond barrier discharge are presented. The spectral characteristics of the radiator in the wavelength range of 160-300 nm and the current and voltage oscillo grams have been studied. The intensity of the radiation of the 175 nm ArCl (B → X) and 258 nm Cl 2 (D' → A') bands were optimized during the variation of pressure and partial composition of the working mixture Ar-CCl 4 , and also the conditions of the ignition of the nanosecond discharge with two dielectric barriers. The main processes of the formation of the argon chloride molecule have been considered in the barrier discharge on the basis of the Ar-CCl 4 mixture.
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