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Composite films and aerogels of polyvinylpyrrolidone/cellulose nanocrystals (PVP/CNC) were prepared by solution casting and freeze-drying, respectively. Investigations into the PVP/CNC composite films and aerogels over a wide composition range were conducted. Thermal stability, morphology, and the resulting reinforcing effect on the PVP matrix were explored. FTIR, TGA, DSC, X-ray diffraction, SEM, and tensile testing were used to examine the properties of the composites. It was revealed PVP-assisted CNC self-assembly that produces uniform CNC aggregates with a high aspect ratio (length/width). A possible model of the PVP-assisted CNC self-assembly has been considered. Dispersibility of the composite aerogels in water and some organic solvents was studied. It was shown that dispersing the composite aerogels in water resulted in stable colloidal suspensions. CNC particles size in the redispersed aqueous suspensions was near similar to the CNC particles size in never-dried CNC aqueous suspensions.

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In this work, a series of polyacrylamide/cellulose nanocrystal (PAM/CNC) composites with a wide range of compositions were prepared by a solution casting method. Subsequently, the influence of the PAM conformation on the behaviour of the PAM/CNC composites was studied. The microstructural, thermal, and mechanical properties of the PAM/CNC composites were also investigated, as well as their flocculation and dispersion behaviour. Thermal degradation of both CNC and PAM in the composites occurred simultaneously, at a much higher temperature than the degradation of the neat CNC. By TEM and SEM, PAM globule aggregates in the PAM/ CNC composites were detected. With an increase in the medium acidity, the PAM globule aggregate size of in the composites decreased. Moreover, the composite films cast from high pH solutions (extended PAM conformation) exhibited superior strength properties than those cast from low pH solutions (contracted coil PAM conformation). The PAM globule conformation provided good re-dispersibility of the freeze-dried PAM/CNC composites by preventing aggregation of the CNC particles. The PAM globule adsorption onto the CNC particles caused CNC surface hydrophobization and a decrease in their surface charge, while maintaining high colloidal stability of the CNC suspensions. Furthermore, the CNC particles with adsorbed PAM were demonstrated to be useful as emulsifiers and compatibilisers.

A single crystal of 25,26,27,28-tetrahydroxycalix[4]arene molecular complex with n-hexane was grown by slow evaporation of a solution in n-hexane allowing a complete elucidation of its structure. For the first time a 25,26,27,28tetrahydroxycalix[4]arene molecular complex with toluene was obtained. In addition, its thermal stability was studied. The kinetic sorption curves of acetone, acetonitrile, nhexane, and toluene saturated vapors within 25,26,27,28-tetrahydroxycalix[4]arene were derived experimentally. It was shown that the kinetic sorption curve of acetonitrile saturated vapor within 25,26,27,28-tetrahydroxycalix[4]arene has a distinct peak corresponding to the 1:1 stoichiometry. It was suggested that the structural reorganization of 25,26,27,28-tetrahydroxycalix[4]arene provides transport of acetonitrile molecules into the molecular crystal and subsequent complexation with the formation of a thermodynamically stable hexagonal structure. A conclusion was drawn that the high thermal stability of 25,26,27,28-tetrahydroxycalix[4]arene solvates is due to strict compliance with the shape and size of the "guest" molecule and "host" cavity size.