The spectroscopic technique for pH measurement is a well-established laboratory technique that can give high-accuracy pH values. Recent studies have shown the advantage of this technique over standard potentiometric methods for pH measurements in fresh water and seawater and also at high temperatures and pressures. However, a limitation of the spectroscopic technique is that a single pH dye is sensitive only over a narrow pH range. We have developed optimized dye mixtures that are both sensitive and accurate over a broad pH range. The measurement is robust and simple, requires a minimum of two wavelengths, and is independent of the volume of the dye mixture added. Optimization of the dye mixture formulation to maximize accuracy in a broad range of pH involves varying both the dye type and its mole fraction and also accounting for spectral noise. This technique has been successfully applied for in situ pH measurements of oilfield formation waters.
The article discusses the problems associated with metrological support of equipment for geophysical research, issues of ensuring the uniformity of well measurements, the creation of Russian standards for calibrating well equipment when determining the porosity coefficients and oil, gas, water saturation, determining the parameters of defects during well cementing and technical condition of casing strings and the water-oil-gas flow. The problems of creating full-fledged methods for measuring the parameters of oil and gas fields with conventional and hard-to-recover reserves have been investigated. The key directions of development of the Russian metrological support of geophysical well measurements were determined. The tasks that need to be solved to create metrological support for geophysical well logging as an industry that meet international standards are indicated. The expediency of creating a Russian Geophysical Center for Metrology and Certification, the need to develop a new and update the existing regulatory framework, which will allow Russian geophysics to reach the level of world leaders in the field of geophysical research, are substantiated.
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