Combustion of high-energy chemical fuels containing dioxins in their elemental composition can lead to the formation of super eco toxicants on smoke particles-polychlorinated dioxins and furans. The choice of the method of solving the equations of chemical kinetics is basic in numerical experiment. Calculation and theoretical studies were carried out to solve the problem of determining the parameters of combustion products of chemical fuels taking into account the formation of traces of polychlorinated dioxins. Basic information on the adopted method of determining non-equilibrium composition of combustion products of chlorine-containing chemical fuels is presented. Based on the literary analysis on the mechanisms and rates of chemical reactions of conversion of chlorine-containing compounds, a kinetic model of formation of traces of dioxins was built. Numerical calculations on the assumption of chemical equilibrium have shown that the dioxins formation process is substantially non-equilibrium. The results of kinetic studies on the emission of dioxins precursors showed the nature of the change in time of various components of combustion products of chemical fuels depending on temperature.
Combustion of high-energy chemical fuels containing chlorine in the element structure can lead to formation in the particles of smoke of super eco toxicants—the polychlorinated dioxins and furans. The numerical experiment conducted was based on solution of the equations of chemical kinetics. The computational and theoretical researches directed to the solution of a problem of determination of parameters of combustion products of chemical fuels taking into account formation of harbingers of the polychlorinated dioxins were executed. The main data on the accepted method of determination of disequilibrium structures of products of burning the chlorine-containing chemical fuels were represented. Based on the analysis of references about mechanisms and speeds of chemical reactions of transformations of chlorine-containing connections, the kinetic model of formation of predecessors of dioxins is constructed. The carried-out calculations showed (assuming chemical balance) that process of formation of dioxins is significantly disequilibrious. The results of kinetic researches on emission of harbingers of dioxins showed the nature of the influence of different components of combustion products of chemical fuels on time for the different levels of temperatures.
In power plants intended for the disposal of solid household waste, the processes take place at a high temperature. For such installations, nonequilibrium processes are characteristic of a change in the composition of combustion products caused by the final rates of the ongoing chemical reactions. This affects the basic characteristics of the combustion process of municipal solid waste. A mathematical model has been created for calculating the chemically nonequilibrium composition of the fuel. Solid household and industrial waste is a high-energy fuel. It is a high energy fuel. The process of thermal neutralization of solid household waste is considered. An alternative calculation method is presented that allows one to find the composition of combustion products under conditions of nonequilibrium in the process of thermal utilization of solid domestic waste. The data on the composition and properties of solid household waste obtained by the developed method of calculation allow predicting the yield of super Eco toxicants in combustion products. On the basis of the equations of formal chemical kinetics, an alternative was created, which consists in determining the composition of combustion products taking into account the kinetics of chemical reactions. The assumption is introduced that transformations in the gas phase are elementary, one-stage. Various chemical interactions can be represented by a set of elementary stages. The most probable are mono-, biand three molecular chemical reactions. The method allows predicting the yield of Eco toxicants by finding the composition of the fuel combustion products prior to its utilization.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.