The component profiles of apricot, grape, and black currant pomace extracts have been analyzed using HPLC coupled to diode-array detection and tandem mass spectrometry (HPLC-DAD-MS). The predominant components in grape, apricot, and black currant pomace extracts were phenolic acids and flavonols. The redox behavior of apricot, black currant, and grape pomace water extracts was evaluated by means of cyclic voltammetry. Also, individual substances mainly present in the extracts were analyzed. The results of electrochemical testing were compared to traditional chemical techniques of potassium ferricyanide reduction (FRAP) and phosphomolybdenum assay, and fair agreement was established. The 2,2-diphenyl-1-picrylhydrazyl (DPPH) radical scavenging assay and 2,2′-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) radical scavenging assays were applied in order to estimate antioxidant activity. The reducing power of the grape extract was found to be higher than that of the apricot and black currant extracts in both potassium ferricyanide reduction (FRAP) and phosphomolybdenum methods.
Optically transparent, crack-free mesoporous titania and zirconia-doped titania thin film photocatalysts were fabricated by sol-gel technique, using nonionic amphiphilic block copolymer Pluronic P123 as template. The structural and optical properties of these films were characterized using SEM, low-angle XRD, and UV/Vis spectroscopy, hexane adsorption investigation. Band gap energy and the position of flatband potentials were estimated by photoelectrochemical measurements. Enhancing of photocatalytic activity of zirconia-doped films relative to pureTiO2originates from an anodic shift of the valence band edge potential. Catalytic activity of mesoporousTiO2andTiO2/ZrO2(5–50% ofZrO2) films in the processes ofCrVItoCrIIIphotoreduction and 2,4-dinitroaniline photooxidation correlates with crystalline size and growth with increasing of specific surface area of the samples.
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