During the late Quaternary, dramatic changes in relative sea level (~170 m) are known to have occurred in the Caspian Sea. However, all previous attempts at resolving the uncertainty associated with the timing of these transgressive/regressive events, primarily using radiocarbon, have produced inconclusive or controversial results. Here we present the first reliable chronology for the largest known transgression (Early Khvalynian). This was derived using optically stimulated luminescence (OSL) analysis of sand‐sized quartz, with support from infrared stimulated luminescence (IRSL) from K‐rich feldspar grains, all extracted from 16 sediment samples collected along the Lower Volga River. These samples were taken from loessic sediments, marine clays (known as Chocolate Clays) and the overlying modern soils exposed at three sections (Srednyaya Akhtuba, Raygorod, Leninsk) ~200 km upstream of the present‐day estuary. The differential bleaching rates of the quartz OSL and feldspar IRSL signals were used to evaluate the degree of resetting of quartz (and feldspar) signals; it was possible to conclude that all signals, and particularly quartz OSL, were sufficiently reset at deposition to allow accurate age estimation. Our results show unambiguously that the Early Khvalynian marine Chocolate Clays present at all three sections were deposited post‐LGM, between ~17 and ~13.1 ka ago. These age estimates are further constrained by those from the overlying Kastanozem soils (9.6–0.7 ka) and underlying loess‐soil series (32–19 ka), confirming a young (17–13 ka) age of the transgressive stage of the Early Khvalynian. Relative sea level during this period must have been well above the sampling altitudes of 11.7 m a.s.l. (Srednyaya Akhtuba), 11.3 m a.s.l. (Raygorod) and 4.7 m a.s.l. (Leninsk) to explain the absence of significant alluvial sand and to allow the deposition of the fine Chocolate Clays marker horizon.
The syngenetic ice and ice-ground composite veins in khasyrey (alas) and interalas plateaus were studied on the second lake-alluvial terrace located in the North of the Gydan Peninsula near the village of Gyda. On the basis of the radiocarbon dating, the time of formation of deposits containing veins from was established – from 16 640 to 854 BP. The peat deposits are mainly represented by the following species: Carex sp., Eriophorum sp., Betula nana, Equisetum sp., Calamagrostis sp., Vaccinium vitis-idaea, Drepanocladus sp., Empetrum sp., Vaccinium uliginosum, Rubus arcticus, Petasites sp. It is established that the polygonal-veined ice of khasyrey and interalas plateaus, except for vertical-striped «clean» ice, contain areas with vertical wavy streaks of ice-ground. Ice of elementary veins and segregation ice were revealed in the composition of veins according to structural and textural features in polarized light. Elementary ice veins compose «clean» ice sections of veins and segregation ice which are their ice-ground sections. Elementary veins are indicative of the predominance of the process of frost cracking during the formation of polygonal-vein ices. The presence of inclusions of ice-ground in the structure of veins points is evidence of a manifestation of local thermokarst processes under the growth of polygonal-vein ice. Ice-ground veins were formed by repeated thawing of the initial ice veins. The formation of ice-ground veins during syngenetic freezing of sediments of the second lake-alluvial terrace is related to uneven manifestation of thermokarst in different facies situations and and climate changes at the Early Pleistocene and Holocene.
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