We report on precision resonance spectroscopy measurements of quantum states of ultracold neutrons confined above the surface of a horizontal mirror by the gravity potential of the Earth. Resonant transitions between several of the lowest quantum states are observed for the first time. These measurements demonstrate, that Newton's inverse square law of Gravity is understood at micron distances on an energy scale of 10 −14 eV. At this level of precision we are able to provide constraints on any possible gravity-like interaction. In particular, a dark energy chameleon field is excluded for values of the coupling constant β > 5.8 × 10 8 at 95% confidence level (C.L.), and an attractive (repulsive) dark matter axion-like spin-mass coupling is excluded for the coupling strength gsgp > 3.7 × 10 −16 (5.3 × 10 −16 ) at a Yukawa length of λ = 20 µm (95% (C.L.).PACS numbers: 12.15. Ji,13.30.Ce,14.20.Dh,23.40.Bw Experiments that rely on frequency measurements can be performed with incredibly high precision. One example is Rabi spectroscopy, a resonance spectroscopy technique to measure the energy eigenstates of quantum systems. It was originally developed by I. Rabi to measure the magnetic moment of molecules [1]. Today, resonance spectroscopy techniques are applied in various fields of science and medicine including nuclear magnetic resonance, masers, and atomic clocks. These methods have opened up the field of low-energy particle physics with studies of particle properties and their fundamental interactions and symmetries. In an attempt to investigate gravity at short distances, we applied the concept of resonance spectroscopy to quantum states of very slow neutrons in the Earth's gravity potential [2]. Here, we present the first precision measurements of gravitational quantum states with this method that we refer to as gravity resonance spectroscopy (GRS). The strength of GRS is that it does not rely on electromagnetic interactions. The use of neutrons as test particles bypasses the electromagnetic background induced by van der Waals and Casimir forces and other polarizability effects.Within this work, we link these new measurements to dark matter and dark energy searches. Observational cosmology has determined the dark matter and dark energy density parameters to an accuracy of two significant figures [3]. While dark energy explains the accelerated expansion of the universe, dark matter is needed in order to describe the rotation curves of galaxies and the largescale structure of the universe. The true nature of dark energy and the content of dark matter remain a mystery, however. The two most obvious candidates for dark energy are either Einstein's cosmological constant [4] or quintessence theories [5,6], where the dynamic vacuum energy changes over time. The resonant frequencies of our quantum states are intimately related to these models. If some as yet undiscovered dark matter or dark energy particles interact with neutrons, this should result in a measurable energy shift of the observed quantum states. One prom...

The electrostatic confinement of massless charge carriers is hampered by Klein tunneling. Circumventing this problem in graphene mainly relies on carving out nanostructures or applying electric displacement fields to open a band gap in bilayer graphene. So far, these approaches suffer from edge disorder or insufficiently controlled localization of electrons. Here we realize an alternative strategy in monolayer graphene, by combining a homogeneous magnetic field and electrostatic confinement. Using the tip of a scanning tunneling microscope, we induce a confining potential in the Landau gaps of bulk graphene without the need for physical edges. Gating the localized states toward the Fermi energy leads to regular charging sequences with more than 40 Coulomb peaks exhibiting typical addition energies of 7–20 meV. Orbital splittings of 4–10 meV and a valley splitting of about 3 meV for the first orbital state can be deduced. These experimental observations are quantitatively reproduced by tight binding calculations, which include the interactions of the graphene with the aligned hexagonal boron nitride substrate. The demonstrated confinement approach appears suitable to create quantum dots with well-defined wave function properties beyond the reach of traditional techniques.

Quantum point contacts are cornerstones of mesoscopic physics and central building blocks for quantum electronics. Although the Fermi wavelength in high-quality bulk graphene can be tuned up to hundreds of nanometres, the observation of quantum confinement of Dirac electrons in nanostructured graphene has proven surprisingly challenging. Here we show ballistic transport and quantized conductance of size-confined Dirac fermions in lithographically defined graphene constrictions. At high carrier densities, the observed conductance agrees excellently with the Landauer theory of ballistic transport without any adjustable parameter. Experimental data and simulations for the evolution of the conductance with magnetic field unambiguously confirm the identification of size quantization in the constriction. Close to the charge neutrality point, bias voltage spectroscopy reveals a renormalized Fermi velocity of ∼1.5 × 106 m s−1 in our constrictions. Moreover, at low carrier density transport measurements allow probing the density of localized states at edges, thus offering a unique handle on edge physics in graphene devices.

Coherent manipulation of the binary degrees of freedom is at the heart of modern quantum technologies. Graphene offers two binary degrees: the electron spin and the valley. Efficient spin control has been demonstrated in many solid-state systems, whereas exploitation of the valley has only recently been started, albeit without control at the single-electron level. Here, we show that van der Waals stacking of graphene onto hexagonal boron nitride offers a natural platform for valley control. We use a graphene quantum dot induced by the tip of a scanning tunnelling microscope and demonstrate valley splitting that is tunable from -5 to +10 meV (including valley inversion) by sub-10-nm displacements of the quantum dot position. This boosts the range of controlled valley splitting by about one order of magnitude. The tunable inversion of spin and valley states should enable coherent superposition of these degrees of freedom as a first step towards graphene-based qubits.

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