Self-organization during friction in complex surface engineered tribosystems is investigated. The probability of self-organization in these complex tribosystems is studied on the basis of the theoretical concepts of irreversible thermodynamics. It is shown that a higher number of interrelated processes within the system result in an increased probability of self-organization

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Adaptive wear-resistant coatings produced by physical vapor deposition (PVD) are a relatively new generation of coatings which are attracting attention in the development of nanostructured materials for extreme tribological applications. An excellent example of such extreme operating conditions is high performance machining of hard-to-cut materials. The adaptive characteristics of such coatings develop fully during interaction with the severe environment. Modern adaptive coatings could be regarded as hierarchical surface-engineered nanostructural materials. They exhibit dynamic hierarchy on two major structural scales: (a) nanoscale surface layers of protective tribofilms generated during friction and (b) an underlying nano/microscaled layer. The tribofilms are responsible for some critical nanoscale effects that strongly impact the wear resistance of adaptive coatings. A new direction in nanomaterial research is discussed: compositional and microstructural optimization of the dynamically regenerating nanoscaled tribofilms on the surface of the adaptive coatings during friction. In this review we demonstrate the correlation between the microstructure, physical, chemical and micromechanical properties of hard coatings in their dynamic interaction (adaptation) with environment and the involvement of complex natural processes associated with self-organization during friction. Major physical, chemical and mechanical characteristics of the adaptive coating, which play a significant role in its operating properties, such as enhanced mass transfer, and the ability of the layer to provide dissipation and accumulation of frictional energy during operation are presented as well. Strategies for adaptive nanostructural coating Topical Review design that enhance beneficial natural processes are outlined. The coatings exhibit emergent behavior during operation when their improved features work as a whole. In this way, as higher-ordered systems, they achieve multifunctionality and high wear resistance under extreme tribological conditions.

Application of the phenomenon of self-organization for the development of wear resistant materials has been reviewed. For this purpose the term of self-organization and dissipative structures as applied to tribology have been discussed. The applications of this phenomenon have been shown in order to develop new wear resistant-and antifriction materials. Specific examples have been shown for the application of the self-organization phenomenon and the generation of dissipative structures for the formation of tribotechnical materials with enhanced wear resistance for current collecting materials and antifriction materials of bearings.

Features of self-organization in the hard AlTiN plasma vapor deposited (PVD) coatings have been investigated under severe frictional conditions associated with high temperatures and stresses, which are typical for high-speed cutting. Aluminum-rich (around 67at.%) (Al67Ti33)N hard PVD coating has been modified by means of the “duplex” post-treatment, including annealing in vacuum at 700°C with subsequent ion implantation by Ar+. Structure modification of the surface layer has been studied using x-ray photoelectron spectroscopy, electron energy loss fine structure, and high resolution electron energy loss spectroscopy methods. Micromechanical characteristics of the coating have been studied using the nanoindentation method. Coefficient of friction was measured in relation to temperature. Wear behavior of the coating has been investigated under severe conditions of HSC of 1040 steel. Results show that the enhancement of nonequilibrium processes during friction due to ion implantation of AlTiN coating by Ar+ leads to a dominating formation of protective triboceramics on the surface with sapphire-like structure that critically improves wear performance. Analytical modeling of the mass transfer within initial stage of wear was performed based on the concept of irreversible thermodynamics and self-organization in order to formulate the principles of friction control.

Abstract:In this paper, we will develop a strategy for controlling the self-organized critical process using the example of extreme tribological conditions caused by intensive build-up edge (BUE) formation that take place during machining of hard-to-cut austentic superduplex stainless steel SDSS UNS32750. From a tribological viewpoint, machining of this material involves intensive seizure and build-up edge formation at the tool/chip interface, which can result in catastrophic tool failure. Built-up edge is considered to be a very damaging process in the system. The periodical breakage of the build-ups may eventually result in tool tip breakage and, thereby, lead to a catastrophe (complete loss of workability) in the system. The dynamic process of build-up edge formation is similar to an avalanche. It is governed by stick-slip phenomenon during friction and associated with the self-organized critical process. Investigation of wear patterns on the frictional surfaces of cutting tools using Scanning Electron Microscope (SEM), combined with chip undersurface characterization and frictional (cutting) force analyses, confirms this hypothesis. The control of self-organized criticality is accomplished through application of a nano-multilayer TiAl60CrSiYN/TiAlCrN thin film Physical Vapor Deposition (PVD) coating containing elevated aluminum content on a cemented carbide tool. The suggested coating enhanced the formation of protective nano-scale tribo-films on the friction surface under operation. Moreover, machining process optimization contributed to further enhancement of this beneficial process, as evidenced by X-ray Photoelectron Spectroscopy (XPS) studies of tribo-films. This resulted in a reduction of the scale of the build ups leading to overall wear performance improvement. A new thermodynamic analysis is proposed concerning entropy production during friction in machining with buildup edge formation. This model is able to predict various phenomena and shows a good agreement with experimental results. In the presented research we demonstrated a novel experimental approach for controlling self-organized criticality using an example of the machining with buildup edge formation, which is similar to avalanches. This was done through enhanced adaptive performance of the surface engineered tribo-system, in the aim of reducing the scale and frequency of the avalanches.

Recently, a family of hard mono-and multilayer TiAlCrSiYN-based coatings have been introduced that exhibit adaptive behavior under extreme tribological conditions (in particular during dry ultrahigh speed machining of hardened tool steels). The major feature of these coatings is the formation of the tribo-films on the friction surface which possess high protective ability under operating temperatures of 1000 C and above. These tribo-films are generated as a result of a selforganization process during friction. But the mechanism how these films affect adaptability of the hard coating is still an open question. The major mechanism proposed in this paper is associated with a strong gradient of temperatures within the layer of nano-scaled tribo-films. This trend was outlined by the performed thermodynamic analysis of friction phenomena combined with the developing of a numerical model of heat transfer within cutting zone based on the finite element method. The results of the theoretical studies show that the major physical-chemical processes during cutting are mostly concentrated within a layer of the tribo-films. This nano-tribological phenomenon produces beneficial heat distribution at the chip/tool interface which controls the tool life and wear behavior.Results of x-ray photoelectron spectroscopy studies indicate enhanced formation of protective sapphire-and mullite-like tribo-films on the friction surface of the multilayer TiAlCrSiYN/TiAlCrN coating. Comprehensive investigations of the structure and phase transformation within the coating layer under operation have been performed, using high resolution transmission electron microscopy, synchrotron radiation technique: x-ray absorption near-edge structure and XRD methods.The data obtained show that the tribo-films efficiently perform their thermal barrier functions preventing heat to penetrate into the body of coated cutting tool. Due to this the surface damaging process as well as non-beneficial phase transformation (formation of AlN hex phase) drastically diminishes within the layer of the adaptive coating. Micro-mechanical properties measurements performed at room and elevated temperatures show that the hardness of the multilayer TiAlCrSiYN/TiAlCrN coating appears stable to 500 C and then drops a little at 600 C but still remains high. It means that if the surface tribo-films can reduce actual temperature down to this level the coating underneath is able to efficiently withstand heavy loads under operation. V C 2012 American Institute of Physics. [http://dx.

Atomic-scale, tribo-ceramic films associated with dissipative structures formation are discovered under extreme frictional conditions which trigger self-organization. For the first time, we present an actual image of meta-stable protective tribo-ceramics within thicknesses of a few atomic layers. A mullite and sapphire structure predominates in these phases. They act as thermal barriers with an amazing energy soaking/dissipating capacity. Less protective tribo-films cannot sustain in these severe conditions and rapidly wear out. Therefore, a functional hierarchy is established. The created tribo-films act in synergy, striving to better adapt themselves to external stimuli. Under a highly complex structure and non-equilibrium state, the upcoming generation of adaptive surface engineered nano-multilayer materials behaves like intelligent systems - capable of generating, with unprecedented efficiency, the necessary tribo-films to endure an increasingly severe environment.