Template cyclomerization of perfluoro-a,b-dicyanostylbene in the presence of trichlorides of IIIa group elements results in formation of pentafluorophenyl substituted boron(III) subpophyrazinate ([(Cl)BsPAF 30 ]) and aluminum(III) and gallium(III) porphyrazinates ([(Cl)MPAF 40 ], M=Al, Ga). Their spectral-luminescence properties are discussed, revealing blue shift of the Q-band and brighter fluorescence comparatively to non-fluorinated analogues. In addition, the molecular structure of trans-perfluoro-a,b-dicyanostylbene was determined by single crystal X-ray diffraction.
Колесник Евгений Анатольевич, кандидат биологических наук, старший научный сотрудник Уральский федеральный аграрный научно-исследовательский центр Уральского отделения Российской академии наук ул. Белинского, д. 112 А, г. Екатеринбург,
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