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(3), where LH = 1-H-2-phenylbenzimidazole, LMe = 1-methyl-2-phenylbenzimidazole, LPh = 1,2-diphenylbenzimidazole, and H 2 dcbpy = 2,2′-bipyridine-4,4′-dicarboxylic acid, has been synthesized and fully characterized by elemental analysis, 1 H and 31 P NMR spectroscopy, mass spectrometry, and single-crystal X-ray analysis. The complexes show strong luminescence in the yellow-orange region in ethanol at room temperature (quantum yield is up to 22 %), and

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