We represent a melting of ultrathin lubricant film by friction between atomically flat surfaces as a result of action of spontaneously appearing elastic field of stress shear component caused by the external supercritical heating. The kinetics of this solid-liquid transition is described by the Maxwell-type and Voigt-Kelvin equations for viscoelastic matter as well as by the relaxation equation for temperature. We show that these equations coincide formally with the synergetic Lorenz system, where the stress acts as the order parameter, the conjugate field is reduced to the elastic shear strain, and the temperature is the control parameter. Using the adiabatic approximation we find the steady-state values of these quantities. Taking into account the deformational defect of the shear modulus, we show that lubricant melting is realized according to mechanism of the first-order transition. The critical temperature of the friction surfaces increases with growth of the characteristic value of shear viscosity and decreases with growth of the shear modulus value linearly.
Manipulation of metal nanoparticles using atomic force microscope is a promising new technique for probing tribological properties at the nanoscale. In spite of some advancements in experimental investigations, there is no unambiguous theoretical treatment of processes accompanying the movement of metallic nanoislands adsorbed on a flat surface and additional research is required. In this paper, we describe computer experiments based on classical molecular dynamics in which the behavior of silver and nickel nanoparticles interacting with a graphene sheet and sheared with constant force is studied. Frictional force acting on the nanoislands is measured as a function of their size. It is shown that its average value grows approximately linearly with contact area, and slopes of linear fits are close to the experimentally observable ones. The dependence of the friction force value and of the shape of the measured friction curves on the type of metal atom is revealed and its possible reasons originating from atomistic background are discussed.
-Melting of an ultrathin lubricant film under friction between atomically smooth surfaces is studied in terms of the Lorentz model. Additive noise associated with shear stresses and strains, as well as with film temperature, is introduced, and a phase diagram is constructed where the noise intensity of the film temperature and the temperature of rubbing surfaces define the domains of sliding, dry, and stick-slip friction. Conditions are found under which stick-slip friction proceeds in the intermittent regime, which is characteristic of selforganized criticality. The stress self-similar distribution, which is provided by temperature fluctuations, is represented with allowance for nonlinear relaxation of stresses and fractional feedbacks in the Lorentz system. Such a fractional scheme is used to construct a phase diagram separating out different types of friction. Based on the study of the fractional Fokker-Planck equation, the conclusion is drawn that stick-slip friction corresponds to the subdiffusion process.
The melting of ultrathin lubricant film by friction between atomically flat surfaces is studied. The additive noises of the elastic shear stress and strain, and the temperature are introduced for building the phase diagrams with the domains of sliding, stick-slip, and dry friction. It is shown that increase of the strain noise intensity causes the lubricant film melting even at low temperatures of the friction surfaces.
Within the framework of Lorentz model for description of viscoelastic medium the influence of deformational defect of the shear modulus is studied on melting of ultrathin lubricant film confined between the atomically flat solid surfaces. The possibility of jump-like and continuous melting is shown. Three modes of lubricant behavior are found, which correspond to the zero shear stress, the Hooke section of loading diagram, and the domain of plastic flow. Transition between these modes can take place according to mechanisms of first-order and second-order phase transformations. Hysteresis of dependencies of stationary stresses on strain and friction surfaces temperature is described. Phase kinetics of the system is investigated. It is shown that ratio of the relaxation times for the studied quantities influences qualitatively on the character of the stationary mode setting.
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