The chemical composition of bottom sediments in the Chukchi and, partly, East Siberian Seas was studied. In the south and west of the Chukchi Sea, a zone has been detected with the accumulation of sediments rich in organic carbon, an increased background content and anomalies of sulfophile metals (Mo, Zn, Hg, Ag, Au), iron-group metals (V, Ni, Co), and some PGE (Ru, Pt). This zone is confined to the neotectonic active system of rift troughs extending from the Bering Strait and eastern Chukchi Peninsula to the continental slope, where it is bounded by the Cenozoic Charlie rift basin of the Canadian hollow. The geochemical features of the carbon-enriched sediments evidence that they formed under oxygen-deficient conditions and, sometimes, in suboxic and anoxic environments near endogenic water and gas sources. The high carbon and metal contents suggest that the very fine-grained sediments in the rift troughs of the Chukchi Sea are a possible analog of some types of ancient highly carbonaceous sediments belonging to black shales.
Arctic sea ice retreat is linked to extrapolar thermal energy import, while the potential impact of pan-Arctic river heat discharge on sea-ice loss has been unresolved. We reconstructed the Holocene history of Arctic sea ice and Russian pan-Arctic river heat discharge, combining ice-rafted debris records and sedimentation rates from the East Siberian Arctic Shelf with a compilation of published paleoclimate and observational data. In the mid-Holocene, the early summer (June–July) solar insolation was higher than that during the late Holocene, which led to a larger heat discharge of the Russian pan-Arctic rivers and contributed to more Arctic sea ice retreat. This intensified decline of early-summer sea ice accelerated the melting of sea ice throughout the summertime by lowering regional albedos. Our findings highlight the important impact of the larger heat discharge of pan-Arctic rivers, which can reinforce Arctic sea-ice loss in the summer in the context of global warming.
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