Several series of tetracatenar mesogens having different lateral substituents (–F, –CN, –CF3) on the central ring have been synthesised and their mesomorphism investigated by polarising microscopy, DSC and small-angle X-ray scattering methods.
Determination of the content of environment polluting chemical agents is of significant importance. The goal of this study was the development of experimental approaches for detection of concentrations of surfaceactive molecules (surfactants) such as sodium dodecyl sulfate (SDS) and
In order to study the influence of molecular structure peculiarities on supramolecular organization and properties in the bulk and thin films of discotic mesogens six new mix-substituted phthalocyanine derivatives with 3,6-dioctyloxyphthalonitrile and 3,4,5,6-tetrachlorophthalonitrile fragments were synthesized. Temperatures of phase transitions, types of mesophase and their dependence on molecule structure, chemical nature, position and ratio of different substituents as well as presence of holmium in the metal complexes were analyzed. The behavior of the studied molecules on the boundary between water and air was investigated and the peculiarity of supramolecular organization in floating layers as well as in thin films was determined. Quenching of luminescence in solutions of the studied compounds in the presence of fullerene C 60 was determined, thus giving prospects for application of these compounds as sensors for fullerene microquantities.
The effect of two types of carbon nanoparticles, i.e., shungite carbon (SC) and multiwalled carbon nanotubes (MWCNTs), on the mesomorphic and rheological properties of cholesteric mesogen in the con centration range of 0.005-0.04 wt % has been reported. The main physical parameters for tribological appli cations, such as phase transition temperature, viscosity, elastic modulus G', loss modulus G'', and complex viscosity η*, have been studied. The preference of using SC as a lubricating coolant additive component has been shown in the comparison with MWCNTs.
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