Thin Titanium films were fabricated on quartz substrates by radio frequency magnetron sputtering under high vacuum. Subsequent annealing at temperatures of 600 ∘C in air resulted in single-phase TiO2 with the structure of rutile, as X-ray diffraction experiment demonstrates. Atomic-force microscopy images verify the high crystalline quality and allow us to determine the grain size even for ultrathin TiO2 films. Rutile has a direct energy band gap at about 3.0–3.2 eV; however, the transitions between the valence and conduction band are dipole forbidden. Just a few meV above that, there is an indirect band gap. The first intense absorption peak appears at about 4 eV. Tauc plots for the position of the indirect band gap show a “blue shift” with decreasing film thickness. Moreover, we find a similar shift for the position of the first absorbance peak studied by the derivative method. The results indicate the presence of quantum confinement effects. This conclusion is supported by theoretical calculations based on a combination of the effective mass theory and the Hartree Fock approximation.
SUMMARYIn the class of (re)scheduling problems where humans constitute the main resource, the scheduling process is influenced by a great number of complex and frequently changing regulations. The complexity and the dynamic nature of these regulations impose the need for an efficient, flexible and user-friendly way to express and manage them. A solution to this problem, in the form of an object-oriented high-level language with semantics highly-tailored to the user needs, is presented. The language, called REDOM, can be applied to different scheduling application domains with a minimum degree of effort, because it is based on a generic meta-model of the resource scheduling problem. An application programming interface facilitates REDOM integration into existing scheduling systems. REDOM is currently being utilised by the DAYSY resource management system, that is implemented as a constraint satisfaction system based on a partial test-and-generate approach. The combination of REDOM and CHIP (Constraint Handling In Prolog), which was used for the implementation of the solution generation subsystem, resulted in a highly-efficient and flexible (re)scheduling system, well-accepted by users.
Thin Mo films in the thickness range between 1 and 164 nm have been deposited on high-quality quartz and Corning glass substrates by Radio Frequency (RF) magnetron sputtering under high vacuum (base pressure ~ 3 × 10-7 mbar). The sputtering target was metallic Mo. Subsequent short annealing of Mo at temperatures between about 400 °C - 600 °C in a muffle furnace in air produced MoO3 thin films. Heating even to 400°C resulted in significant growth of crystal size. Surprisingly, films thinner than about 50 nm could not be heated at higher temperatures due to the evaporation of the oxide. Ultraviolet – visible light absorption spectroscopy experiments were employed for the determination of the optical band gap. The results for direct and indirect allowed transitions are discussed.
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