In this paper a novel variable selection method based on Radial Basis Function (RBF) neural networks and genetic algorithms is presented. The fuzzy means algorithm is utilized as the training method for the RBF networks, due to its inherent speed, the deterministic approach of selecting the hidden node centers and the fact that it involves only a single tuning parameter. The trade-off between the accuracy and parsimony of the produced model is handled by using Final Prediction Error criterion, based on the RBF training and validation errors, as a fitness function of the proposed genetic algorithm. The tuning parameter required by the fuzzy means algorithm is treated as a free variable by the genetic algorithm. The proposed method was tested in benchmark data sets stemming from the scientific communities of time-series prediction and medicinal chemistry and produced promising results.
The absolute luminescence efficiency (AE) of a calcium fluoride (CaF2:Eu) single crystal doped with europium was studied using X-ray energies met in general radiography. A CaF2:Eu single crystal with dimensions of 10 × 10 × 10 mm3 was irradiated by X-rays. The emission light photon intensity of the CaF2:Eu sample was evaluated by measuring AE within the X-ray range from 50 to 130 kV. The results of this work were compared with data obtained under similar conditions for the commercially employed medical imaging modalities, Bi4Ge3O12 and Lu2SiO5:Ce single crystals. The compatibility of the light emitted by the CaF2:Eu crystal, with the sensitivity of optical sensors, was also examined. The AE of the 10 × 10 × 10 mm3 CaF2:Eu crystal peaked in the range from 70 to 90 kV (22.22 efficiency units; E.U). The light emitted from CaF2:Eu is compatible with photocathodes, charge coupled devices (CCD), and silicon photomultipliers, which are used as radiation sensors in medical imaging systems. Considering the AE results in the examined energies, as well as the spectral compatibility with various photodetectors, a CaF2:Eu single crystal could be considered for radiographic applications, including the detection of charged particles and soft gamma rays.
Quantum dots (QDs) are quite interesting materials due to their unique chemical and physical properties. ZnCuInS/ZnS QDs can be produced either in hydrophobic or hydrophilic form, are non-toxic, and thus favorable for studies in the area of biology. Poly(methyl methacrylate) (PMMA) is a well-known biocompatible resin which is widely used in dentistry, ophthalmology, and orthopedic surgery. Four composite PMMA films of ZnCuInS/ZnS nanocrystals with maximum emission at 530 nm and concentrations of 1.0, 4.0, 6.0, and 10.0 %w/v, were prepared. X-ray irradiation was used to evaluate the volume homogeneity of the final samples, as a measure of QD dispersion. The luminescent efficiency was evaluated, under ultraviolet (UV) irradiation. The process of UV irradiation involved the experimental measurement of the forward luminescent light, as well as the backward luminescent light, in order to accurately calculate the energy quantum efficiency (EQE) of ZnCuInS/ZnS QDs. Reflected UV radiation was also measured, and results showed that it ranges from 2% to 6% approximately as the QD concentration rises from 1.0 %w/v to 10.0 %w/v. Beyond 6.0 %w/v, the reflected UV radiation remains essentially unchanged. Additionally, the reflected UV radiation remained unaffected as the power of the incident UV increased. Approximately 9% of incident UV radiation passed through the 1.0 %w/v sample, whereas for the samples with higher ZnCuInS/ZnS concentration, 0% UV radiation passed through. The EQE reached a maximum of about 45% with the 10.0 %w/v sample, while it remained practically unaffected relative to the increase of the emitted UV power. The homogeneity measurements revealed that the coefficient of variation (CV) increased with increasing concentration, for the 1.0, 4.0, and 6.0 %w/v samples. The minimum CV was obtained for the sample of 10.0 %w/v due to the incorporation of sonication in the final product, during the fabrication process.
In this study, the light output of a zinc selenide activated with tellurium (ZnSe: Te) single crystal was measured for X-ray radiography applications. A cubic crystal (10 × 10 × 10 mm) was irradiated using X-rays with tube voltages from 50 to 130 kV. The resulting energy absorption efficiency, detective quantum efficiency, and absolute luminescence efficiency were compared to published data for equally sized GSO: Ce (gadolinium orthosilicate) and BGO (bismuth germanium oxide) crystals. The emitted light was examined to estimate the spectral compatibility with widely used optical sensors. Energy absorption efficiency and detective quantum efficiency of ZnSe: Te and BGO were found to be similar, within the X-ray energies in question. Light output of all three crystals showed a tendency to increase with increasing X-ray tube voltage, but ZnSe: Te stood at least 2 EU higher than the others. ZnSe: Te can be coupled effectively with certain complementary metal–oxide–semiconductors (CMOS), photocathodes, and charge-coupled-devices (CCD), as the effective luminescence efficiency results assert. These properties render the material suitable for various imaging applications, dual-energy arrays included.
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