The chemistry of iron has an active area of research, particularly in the fields of catalysis and biochemistry. This review includes eighty-five double salts of iron and over eight hundred and fifty heterobinuclear iron compounds of known crystal structure. The heterometal atoms include non -transition and transition metals, as well as lanthanides and actinides. Correlations between structural parameters, heterometal and ligand donor atoms are developed and an overall summary of the metal -metal distances is given.
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