Nano-graphite sheets (NanoGs) were prepared by treating the expanded graphite with sonication in 95% alcohol solution. The polypyrrole (PPy)/NanoGs/TbCl 3 nanocomposites were successfully prepared by in-situ polymerization. The structure, morphology, and stability of the composites are characterized by transmission electron microscope (TEM), scanning electron microscope (SEM), and thermogravimetric analysis (TG). The PPy/NanoGs/TbCl 3 nanocomposites exhibited much higher electrical conductivity and better thermal property than the pristine PPy. The electrical conductivity of these nanocomposites were adjusted by changing different wt% of the NanoGs and TbCl 3 , the conductivity of the composites was reached 80.0 S/cm with the 7 wt% of TbCl 3 and 3 wt% of NanoGs.
Under the COMPASS (condensed-phase optimized molecular potentials for atomistic simulation studies) force field, the MD (molecular dynamics) simulation was applied to Polyaniline/ Graphite Composites. In this paper, we briefly introduced the constructive process of the composite system by means of MD simulation. The stability and mechanism of five intercalation composites were studied with microcosmic figure and variational energy under the invariable NVT ensemble. The results indicate that the area of graphite sheets is particularly important in the intercalation bonding process. It is the key to control the final product. The area selection is based on the molecular weight and volume of the intercalated organic polymer.
Cellulose/Ag/polyaniline conductive composite with rather excellent electrical conductivity was heterogeneously synthesized in this paper. The UV-Vis analysis indicated that homogeneous nanoAg particles deposited on the surface of cellulose in the form of globe particles. They offered some electrons to polyaniline chains. This behavior resulted to the facts that more polyaniline embedded on cellulose and an integrated electrically conductive network formed. Consequently, the high electrical conductivity of the composite was observed. The value was 3.48 S/cm, which was higher two magnitudes than the electrical conductivity of cellulose/polyaniline composite (2.15×10-2S/cm), and even was higher than the electrical conductivity of pure polyaniline (0.142 S/cm). This paper provided a facile method for the preparation of cellulose/Ag/ polyaniline composite with favorable electrical conductivity.
A novel structure of nan0Composite consisting of conducting Polyaniline (PANI), graphite nanosheets (NanoGs) and Eu3+ was synthesized through emulsion polymerization. NanoGs were prepared via powdering the expanded graphite with the aid of sonication in aqueous ethanol solution. Then NanoGs and rare earth ions (Eu3+) were directly organised with sonication, using p-toluene-sulfonic acid (P-TSA) as an emulsifier and dopant, (NH4)2S2O8 as inducing reagent and the polymerization of aniline monomer simultaneously. The product was characterized by transmission electron microscope (TEM), X-ray diffraction (XRD), Fouier transform infrared spectroscopy (FT-IR), and thermal gravimetric analysis (TGA). From the thermogravmetric analysis, the introduction of NanoGs and rare-earth ions (Eu3+) exhibited a beneficial effect on the thermal stability of pure PANI.
A series of conductive composites polyaniline(PANI)-cellulose were heterogeneously synthesized by chemical oxidative polymerization of aniline with native cellulose pretreated by ultrasonic. The morphology and chemical structure of the composites were examined by SEM and FTIR. TGA was used to study their thermal properties. The electrical conductivity was measured at room temperature by the standard four-probe method. For the sake of illuminating the influence of ultrasonic pretreatment on the structure and properties of PANI-cellulose composites, the SEM microphotographs, FTIR spectrum and TG curve of the PANI-cellulose composites prepared with native cellulose without any treatment were also shown in this paper to serve as reference. The PANI content and electrical conductivity of these two composites were also compared. It was found that cellulose surface was severely eroded by ultrasonic wave, and PANI homogeneously dispersed on this eroded cellulose surface in the form of particles. In reverse, the PANI particles loaded on the surface of untreated cellulose with evident aggregation. The homogeneous dispersion of PANI particles would be favor for the improvement of the electrical conductivity of the composites. From the FTIR spectra, it was verified that there was no difference between these two composites. It indicated that ultrasonic force did not lead to the variation of the chemical structure of cellulose. TG curves revealed that the thermal stability of PANI-cellulose composites was obviously enhanced than pure cellulose due to the protection of PANI particles deposited on its surface. Nevertheless, ultrasonic has a negative effect on the thermal stability of the composites, which resulted in the long cellulose molecular chains change into shorter ones, so the decomposition of composite occurred at lower temperature. It was because that ultrasonic pretreatment contributed to the homogeneous dispersion of PANI and more PANI particle depositing on the cellulose surface. Therefore, the PANI-cellulose composites with ultrasonic pretreated cellulose have more PANI content and higher electrical conductivity than the composites with untreated cellulose. Moreover, the difference of these two factors between the two composites became more and more marked with increasing of the amount of aniline. When aniline used was up to 0.5 g, the PANI content in the former was 48.2% more than the latter. This work provided a facile method for the synthesis of PANI-cellulose conductive composites with excellent conductivity.
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