The doping of foreign cations and anions is one of the effective strategies for engineering defects and modulating the optical, electronic, and surface properties that directly govern the photocatalytic O 2 and H 2 evolution reactions. BaTaO 2 N (BTON) is a promising 600 nm-class photocatalyst because of its absorption of visible light up to 660 nm, small band gap (E g = 1.9 eV), appropriate valence band-edge position for oxygen evolution, good stability under light irradiation in concentrated alkaline solutions, and nontoxicity. Although the photocatalytic and photoelectrochemical water-splitting efficiencies of BaTaO 2 N have been progressively improved, it is still far from the requirements set for practical applications. Here, we employ a 5% B site-selective doping of aliovalent metal cations (Al 3+ , Ga 3+ , Mg 2+ , Sc 3+ , and Zr 4+ ) to enhance sacrificial visible light-induced photocatalytic H 2 and O 2 evolution over BaTaO 2 N. The results of physicochemical characterizations reveal that no significant change in crystal structure, crystal morphology, and optical absorption edge is observed upon cation doping. Therefore, the difference observed in O 2 and H 2 evolution during the photocatalytic reactions over pristine and doped BaTaO 2 N photocatalysts is explained by examining optical, electronic, and surface properties. Also, molecular dynamics (MD) is used to gain insights into the respective effect of cation doping on adsorption energy of water molecules and formed intermediates (H* for H 2 evolution and HO*, O*, and HOO* for O 2 evolution) on the BaTaO 2 N surfaces terminated with TaO 6 , TaN 6 , and TaO 4 N 2 octahedra. Finally, the experimental reaction rates for H 2 and O 2 evolution are correlated well using a linear energy−performance relationship, elucidating the doping and surface-termination trends observed in the BaTaO 2 N photocatalysts.

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TiO2-supported activated carbon felts (TiO2-ACFTs) were prepared by dip coating of felts composed of activated carbon fibers (ACFs) with either polyester fibers (PS-A20) and/or a polyethylene pulp (PE-W15) in a TiO2 aqueous suspension followed by calcination at 250 °C for 1 h. The as-prepared TiO2-ACFTs with 29-35 wt.% TiO2 were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and N2 adsorption. The TiO2-ACFT(PS-A20) samples with 0 and 29 wt.% TiO2 were microporous with specific surface areas (S BET) of 996 and 738 m(2)/g, respectively, whereas the TiO2-ACFT(PE-W15) samples with 0 and 35 wt.% TiO2 were mesoporous with S BET of 826 and 586 m(2)/g, respectively. Adsorption and photocatalytic activity of the as-prepared samples were evaluated by measuring adsorption in the dark and photodegradation of gaseous acetaldehyde (AcH) and methylene blue (MB) in aqueous solution under UV light. The TiO2 loading caused a considerable decrease in the S BET and MB adsorption capacity along with an increase in MB photodegradation and AcH mineralization. Lemna minor was chosen as a representative aquatic plant for ecotoxicity tests measuring detoxification of water obtained from the MB photodegradation reaction with the TiO2-ACFT samples under UV light.