Peridotite xenoliths from the Nó grá d-Gö mö r Volcanic Field (NGVF) record the geochemical evolution of the subcontinental lithospheric mantle beneath the northern margin of the Pannonian Basin. This study is focused on spinel lherzolites and presents petrography, and major and trace element geochemistry for 51 xenoliths selected from all xenolith-bearing localities of the NGVF. The xenoliths consist of olivine, orthopyroxene, clinopyroxene and spinel 6 amphibole. No correlations between modal composition and textures were recognized; however, major and trace element geochemistry reveals several processes, which allow the distinction of xenolith groups with different geochemical evolution. The xenoliths have undergone varying degrees ($7-25%) of partial melting with overprinting by different metasomatic processes. Based on their Mg#, the xenoliths can be subdivided into two major groups. Group I has olivine Mg# between 89 and 91, whereas Group II has Mg# <89, significant enrichment of Fe and Mn in olivine and pyroxenes, and high Ti in spinel. Trace element contents of the xenoliths vary widely, allowing a further division based on light rare earth element (LREE) enrichment or depletion in pyroxenes. REE patterns of amphiboles match those of clinopyroxenes in each xenolith where they appear, and are inferred to have different origins based on their Nb (and other high field strength element) contents. It is proposed that Nb-poor amphiboles record the oldest metasomatic event, caused by subduction-related volatilebearing silicate melts or fluids, followed by at least two further metasomatic processes: one that resulted in U-Th-(Nb-Ta)-LREE enrichment and crystallization of Nb-rich amphibole, affecting
Ureilite meteorites are arguably our only large suite of samples from the mantle of a dwarf planet and typically contain greater abundances of diamond than any known rock. Some also contain lonsdaleite, which may be harder than diamond. Here, we use electron microscopy to map the relative distribution of coexisting lonsdaleite, diamond, and graphite in ureilites. These maps show that lonsdaleite tends to occur as polycrystalline grains, sometimes with distinctive fold morphologies, partially replaced by diamond + graphite in rims and cross-cutting veins. These observations provide strong evidence for how the carbon phases formed in ureilites, which, despite much conjecture and seemingly conflicting observations, has not been resolved. We suggest that lonsdaleite formed by pseudomorphic replacement of primary graphite shapes, facilitated by a supercritical C-H-O-S fluid during rapid decompression and cooling. Diamond + graphite formed after lonsdaleite via ongoing reaction with C-H-O-S gas. This graphite > lonsdaleite > diamond + graphite formation process is akin to industrial chemical vapor deposition but operates at higher pressure (∼1–100 bar) and provides a pathway toward manufacture of shaped lonsdaleite for industrial application. It also provides a unique model for ureilites that can reconcile all conflicting observations relating to diamond formation.
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